{"id":4834,"date":"2026-06-03T06:24:36","date_gmt":"2026-06-03T05:24:36","guid":{"rendered":"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/initiation\/"},"modified":"2026-06-28T05:50:12","modified_gmt":"2026-06-28T04:50:12","slug":"initiation","status":"publish","type":"page","link":"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/initiation\/","title":{"rendered":"Initiation"},"content":{"rendered":"\n<section class=\"ols-revision-page ols-initiation-page\">\n  <style>\n    .ols-revision-page {\n      --navy: #1C244B;\n      --blue: #2563eb;\n      --soft-blue: #eef4ff;\n      --soft-red: #fff7f7;\n      --soft-purple: #f7f0ff;\n      --soft-green: #f0f7f1;\n      --soft-yellow: #fff8e6;\n      --red: #c81e1e;\n      --gold: #c9973a;\n      --green: #3f8f46;\n      --grey-text: #667085;\n      --body-text: 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{\n      width:92px;\n      height:92px;\n      border-radius:50%;\n      object-fit:cover;\n      object-position:center;\n      flex-shrink:0;\n      border:4px solid #ffffff;\n      box-shadow:\n        0 14px 32px rgba(28,36,75,0.18),\n        0 0 0 1px rgba(28,36,75,0.10);\n      transition:\n        transform 0.25s ease,\n        box-shadow 0.25s ease;\n    }\n\n    .ols-author:hover .ols-author-avatar-img {\n      transform:scale(1.04);\n      box-shadow:\n        0 20px 42px rgba(28,36,75,0.22),\n        0 0 0 1px rgba(28,36,75,0.10);\n    }\n\n    .ols-author-content {\n      min-width:0;\n    }\n\n    .ols-author-title {\n      margin:0 0 4px;\n      font-size:clamp(24px,3vw,34px);\n      line-height:1.15;\n      font-weight:700;\n      color:#1C244B;\n      letter-spacing:-0.03em;\n    }\n\n    .ols-author-description {\n      margin:0;\n      font-size:17px;\n      line-height:1.7;\n      font-weight:300;\n      color:#667085;\n    }\n\n    .ols-linkedin-pill {\n      display:inline-flex;\n      align-items:center;\n      justify-content:center;\n      gap:10px;\n      margin-top:16px;\n      padding:11px 18px;\n      border-radius:999px;\n      background:linear-gradient(135deg,#0A66C2,#004182);\n      color:#ffffff !important;\n      text-decoration:none;\n      font-size:14px;\n      line-height:1;\n      font-weight:700;\n      letter-spacing:0.01em;\n      box-shadow:0 10px 22px rgba(10,102,194,0.24);\n      position:relative;\n      overflow:hidden;\n      transition:\n        transform 0.22s ease,\n        box-shadow 0.22s ease;\n    }\n\n    .ols-linkedin-pill::before {\n      content:\"\";\n      position:absolute;\n      top:0;\n      left:-120%;\n      width:100%;\n      height:100%;\n      background:linear-gradient(\n        120deg,\n        rgba(255,255,255,0) 0%,\n        rgba(255,255,255,0.28) 50%,\n        rgba(255,255,255,0) 100%\n      );\n      transition:left 0.7s ease;\n    }\n\n    .ols-linkedin-pill:hover {\n      transform:translateY(-3px) scale(1.03);\n      color:#ffffff !important;\n      box-shadow:\n        0 16px 34px rgba(10,102,194,0.34),\n        0 0 0 6px rgba(10,102,194,0.10);\n    }\n\n    .ols-linkedin-pill:hover::before {\n      left:120%;\n    }\n\n    .ols-linkedin-icon {\n      width:18px;\n      height:18px;\n      display:block;\n      flex-shrink:0;\n    }\n<\/style>\n\n  <aside class=\"ols-sidebar\">\r\n  <div class=\"ols-sidebar-header\">\r\n    <h3>Revision Notes<\/h3>\r\n    <p>A Level Chemistry<\/p>\r\n  <\/div>\r\n\r\n  <div class=\"ols-topic-group\">\r\n    <h4>Topic 6 Organic Chemistry I<\/h4>\r\n\r\n    <ul class=\"ols-topic-list\">\r\n\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/\">Introduction to Organic Chemistry<\/a>\r\n\r\n        <ul class=\"ols-subtopic-list\">\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/iupac-rules\/\">IUPAC Rules<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/alkene\/\">Alkene<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/alcohol\/\">Alcohol<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/halogenoalkanes\/\">Halogenoalkanes<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/aldehyde\/\">Aldehyde<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/ketone\/\">Ketone<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/carboxylic-acid\/\">Carboxylic Acid<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/ester\/\">Ester<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/introduction-to-organic-chemistry\/isomerism\/\">Isomerism<\/a>\r\n          <\/li>\r\n        <\/ul>\r\n      <\/li>\r\n\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/\">Alkanes<\/a>\r\n\r\n        <ul class=\"ols-subtopic-list\">\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/crude-oil\/\">Alkanes from Crude Oil<\/a>\r\n\r\n            <ul class=\"ols-subtopic-list\">\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/crude-oil\/fractional-distillation\/\">Fractional Distillation<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/crude-oil\/cracking\/\">Cracking<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/crude-oil\/reforming\/\">Reforming<\/a>\r\n              <\/li>\r\n            <\/ul>\r\n          <\/li>\r\n\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/fuel\/\">Alkanes as Fuel<\/a>\r\n\r\n            <ul class=\"ols-subtopic-list\">\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/fuel\/combustion\/\">Combustion<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/fuel\/oxides-of-sulfur\/\">Oxides of Sulfur<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/fuel\/oxides-of-nitrogen\/\">Oxides of Nitrogen<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/fuel\/catalytic-converter\/\">Catalytic Converter<\/a>\r\n              <\/li>\r\n            <\/ul>\r\n          <\/li>\r\n\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/alternative-fuel\/\">Alternative Fuel<\/a>\r\n          <\/li>\r\n\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/\">Reactions of Alkanes<\/a>\r\n\r\n            <ul class=\"ols-subtopic-list\">\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/free-radical-substitution\/\">Free Radical Substitution<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/initiation\/\">Initiation<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/propagation\/\">Propagation<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/termination\/\">Termination<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/further-substitution\/\">Further Substitution<\/a>\r\n              <\/li>\r\n            <\/ul>\r\n          <\/li>\r\n        <\/ul>\r\n      <\/li>\r\n\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/\">Alkenes<\/a>\r\n\r\n        <ul class=\"ols-subtopic-list\">\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/alkene-bonding\/\">Alkene Bonding<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/geometric-isomerism\/\">Geometric Isomerism<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/electrophilic-addition-mechanism\/\">Electrophilic Addition Mechanism<\/a>\r\n          <\/li>\r\n\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/\">Reactions of Alkenes<\/a>\r\n\r\n            <ul class=\"ols-subtopic-list\">\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/halogens\/\">Halogens<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/hydrogen-halide\/\">Hydrogen Halide<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/bromine-water\/\">Bromine Water<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/hydrogen\/\">Hydrogen<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/steam\/\">Steam<\/a>\r\n              <\/li>\r\n              <li>\r\n                <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/reactions-of-alkenes\/kmno4\/\">KMnO4<\/a>\r\n              <\/li>\r\n            <\/ul>\r\n          <\/li>\r\n\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/polymerisation-reactions\/\">Polymerisation Reactions<\/a>\r\n          <\/li>\r\n          <li>\r\n            <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/polymer-waste\/\">Polymer Waste<\/a>\r\n          <\/li>\r\n        <\/ul>\r\n      <\/li>\r\n\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/halogenoalkanes\/\">Halogenoalkanes<\/a>\r\n      <\/li>\r\n\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alcohols\/\">Alcohols<\/a>\r\n      <\/li>\r\n\r\n    <\/ul>\r\n  <\/div>\r\n\r\n  <div class=\"ols-topic-group\">\r\n    <h4>Next Topics<\/h4>\r\n\r\n    <ul class=\"ols-topic-list\">\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-7-modern-analytical-techniques-i\/\">Topic 7 Modern Analytical Techniques I<\/a>\r\n      <\/li>\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-5-formulae-equations-and-amounts-of-substance\/\">Topic 5 Formulae, Equations &amp; Amounts<\/a>\r\n      <\/li>\r\n      <li>\r\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-4-inorganic-chemistry-and-the-periodic-table\/\">Topic 4 Inorganic Chemistry &amp; The Periodic Table<\/a>\r\n      <\/li>\r\n    <\/ul>\r\n  <\/div>\r\n<\/aside>\r\n\r\n<script>\r\n(function() {\r\n  function normalisePath(path) {\r\n    return String(path || '')\r\n      .split('?')[0]\r\n      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href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/\">Revision Notes<\/a> \/\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/\">A Level Chemistry<\/a> \/\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/\">Edexcel<\/a> \/\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/\">Topic 6 Organic Chemistry I<\/a> \/\n        <a href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/free-radical-substitution\/\">Reactions of Alkanes<\/a> \/\n        <span>Initiation<\/span>\n      <\/nav>\n\n      <header class=\"ols-title-card\">\n        <h1>Initiation<\/h1>\n        <p class=\"ols-page-intro\">A concise revision guide to the initiation step in free-radical substitution, including UV light, homolytic fission, halogen radicals and how unpaired electrons are represented.<\/p>\n\n        <div class=\"ols-badges\">\n          <div class=\"ols-badge\">Paper 2<\/div>\n          <div class=\"ols-badge\">Topic 6: Organic Chemistry I<\/div>\n          <div class=\"ols-badge\">9CH0\/02<\/div>\n        <\/div>\n\n                <div class=\"ols-author\">\n          <img decoding=\"async\"\n            class=\"ols-author-avatar-img\"\n            src=\"https:\/\/www.onlinelearningsystem.net\/xyz\/wp-content\/uploads\/2026\/05\/Author-Profile.jpeg\"\n            alt=\"Dr. Mohammed Al-Fatah\"\n          >\n\n          <div class=\"ols-author-content\">\n            <h2 class=\"ols-author-title\">Written by: Dr. Mohammed Al-Fatah<\/h2>\n            <p class=\"ols-author-description\">Chemistry specialist revision notes for A Level Chemistry.<\/p>\n\n            <a class=\"ols-linkedin-pill\" href=\"https:\/\/www.linkedin.com\/in\/doctormohammedfatah\/\" target=\"_blank\" rel=\"noopener noreferrer\">\n              <svg class=\"ols-linkedin-icon\" viewBox=\"0 0 24 24\" fill=\"currentColor\" aria-hidden=\"true\">\n                <path d=\"M4.98 3.5C4.98 4.88 3.86 6 2.48 6S0 4.88 0 3.5 1.12 1 2.48 1s2.5 1.12 2.5 2.5zM.5 8h4V24h-4V8zm7 0h3.8v2.2h.1c.5-.9 1.8-2.2 3.9-2.2 4.2 0 5 2.8 5 6.4V24h-4v-7.6c0-1.8 0-4.2-2.6-4.2s-3 2-3 4v7.8h-4V8z\"\/>\n              <\/svg>\n              View LinkedIn Profile\n            <\/a>\n          <\/div>\n        <\/div>\n      <\/header>\n\n      <article class=\"ols-note-card soft\">\n        <div class=\"ols-note-title\">\n          <div class=\"ols-note-icon\">1<\/div>\n          <h2>What Happens During Initiation?<\/h2>\n        <\/div>\n\n        <p><strong>Initiation<\/strong> is the first step in the free-radical substitution mechanism. It produces the free radicals needed to start the chain reaction.<\/p>\n        <p>In this step, a halogen molecule absorbs energy from <strong>ultraviolet, UV, light<\/strong>. The energy breaks the halogen-halogen bond by <strong>homolytic fission<\/strong>.<\/p>\n        <p>For chlorine, the initiation equation is:<\/p>\n\n        <div class=\"ols-definition-box\">\n          <p><strong>Initiation equation:<\/strong> Cl<sub>2<\/sub> \u2192 2Cl\u2022<\/p>\n        <\/div>\n\n        <div class=\"ols-key-box\">\n          <p><strong>Key idea:<\/strong> Initiation does not directly make the haloalkane product. It produces the reactive halogen radicals that allow the next stage, propagation, to begin.<\/p>\n        <\/div>\n      <\/article>\n\n      <article class=\"ols-note-card\">\n        <div class=\"ols-note-title\">\n          <div class=\"ols-note-icon\">2<\/div>\n          <h2>Why UV Light Breaks the Halogen Bond<\/h2>\n        <\/div>\n\n        <p>UV light provides enough energy to break the <strong>Cl-Cl<\/strong> bond in chlorine or the <strong>Br-Br<\/strong> bond in bromine.<\/p>\n        <p>In chlorination, the Cl-Cl bond is broken in preference to other bonds because it is the <strong>weakest bond present<\/strong> in the starting mixture. UV light does not have sufficient energy to break the much stronger <strong>C-H<\/strong> bond in the alkane under these conditions.<\/p>\n\n        <div class=\"ols-table-wrap\">\n          <table class=\"ols-table\">\n            <thead>\n              <tr>\n                <th>Bond considered<\/th>\n                <th>What UV light does<\/th>\n                <th>Importance in initiation<\/th>\n              <\/tr>\n            <\/thead>\n            <tbody>\n              <tr>\n                <td data-label=\"Bond considered\"><strong>Cl-Cl or Br-Br<\/strong><\/td>\n                <td data-label=\"What UV light does\">Breaks the halogen-halogen bond by homolytic fission.<\/td>\n                <td data-label=\"Importance in initiation\">Forms halogen free radicals, such as Cl\u2022 or Br\u2022.<\/td>\n              <\/tr>\n              <tr>\n                <td data-label=\"Bond considered\"><strong>C-H<\/strong><\/td>\n                <td data-label=\"What UV light does\">Does not break this bond during initiation.<\/td>\n                <td data-label=\"Importance in initiation\">The C-H bond is stronger, so it is not the bond selected by UV light at this stage.<\/td>\n              <\/tr>\n            <\/tbody>\n          <\/table>\n        <\/div>\n\n        <div class=\"ols-warning-box\">\n          <p><strong>Exam focus:<\/strong> Do not write that UV light breaks a C-H bond in the initiation step. The initiation step breaks the halogen-halogen bond.<\/p>\n        <\/div>\n      <\/article>\n\n      <article class=\"ols-note-card purple\">\n        <div class=\"ols-note-title\">\n          <div class=\"ols-note-icon\">3<\/div>\n          <h2>Homolytic Fission<\/h2>\n        <\/div>\n\n        <p>The halogen-halogen bond breaks by <strong>homolytic fission<\/strong>. This means that each atom takes one electron from the shared covalent bond.<\/p>\n        <p>Because each atom receives one electron, the products are not ions. Instead, the products are <strong>free radicals<\/strong> with unpaired electrons.<\/p>\n\n        <div class=\"ols-definition-box\">\n          <p><strong>Homolytic fission:<\/strong> bond breaking in which each atom takes one electron from the shared covalent bond.<\/p>\n        <\/div>\n\n        <div class=\"ols-figure-card\">\n          <div class=\"ols-figure-image\">\n            <img decoding=\"async\" src=\"https:\/\/www.onlinelearningsystem.net\/xyz\/wp-content\/uploads\/2026\/05\/Homolytic-Fission.webp\" alt=\"Homolytic fission showing each atom taking one electron from a covalent bond to form free radicals.\">\n          <\/div>\n          <div class=\"ols-figure-caption\">\n            <p>Each atom receives one electron from the shared pair, producing two free radicals rather than ions.<\/p>\n          <\/div>\n        <\/div>\n      <\/article>\n\n      <article class=\"ols-note-card green\">\n        <div class=\"ols-note-title\">\n          <div class=\"ols-note-icon\">4<\/div>\n          <h2>Free Radicals Formed in Initiation<\/h2>\n        <\/div>\n\n        <p>A <strong>free radical<\/strong> is a reactive species with an <strong>unpaired electron<\/strong>. This unpaired electron is represented using a dot, such as Cl\u2022 or Br\u2022.<\/p>\n        <p>Free radicals have <strong>no overall charge<\/strong>. The dot shows the unpaired electron, not a positive or negative charge.<\/p>\n\n        <div class=\"ols-table-wrap\">\n          <table class=\"ols-table\">\n            <thead>\n              <tr>\n                <th>Halogen molecule<\/th>\n                <th>Initiation equation<\/th>\n                <th>Radical formed<\/th>\n              <\/tr>\n            <\/thead>\n            <tbody>\n              <tr>\n                <td data-label=\"Halogen molecule\"><strong>Chlorine, Cl<sub>2<\/sub><\/strong><\/td>\n                <td data-label=\"Initiation equation\">Cl<sub>2<\/sub> \u2192 2Cl\u2022<\/td>\n                <td data-label=\"Radical formed\">Chlorine radicals, Cl\u2022<\/td>\n              <\/tr>\n              <tr>\n                <td data-label=\"Halogen molecule\"><strong>Bromine, Br<sub>2<\/sub><\/strong><\/td>\n                <td data-label=\"Initiation equation\">Br<sub>2<\/sub> \u2192 2Br\u2022<\/td>\n                <td data-label=\"Radical formed\">Bromine radicals, Br\u2022<\/td>\n              <\/tr>\n            <\/tbody>\n          <\/table>\n        <\/div>\n\n        <div class=\"ols-key-box\">\n          <p><strong>Remember:<\/strong> The dot must stay with the radical symbol. It represents the unpaired electron that makes the species highly reactive.<\/p>\n        <\/div>\n      <\/article>\n\n      <article class=\"ols-note-card yellow\">\n        <div class=\"ols-note-title\">\n          <div class=\"ols-note-icon\">5<\/div>\n          <h2>Writing the Initiation Step Correctly<\/h2>\n        <\/div>\n\n        <p>When writing initiation, keep the equation simple and specific. The reactant is the halogen molecule, and the products are two halogen radicals.<\/p>\n        <p>For chlorination, the correct initiation step is:<\/p>\n\n        <div class=\"ols-definition-box\">\n          <p><strong>Cl<sub>2<\/sub> \u2192 2Cl\u2022<\/strong><\/p>\n        <\/div>\n\n        <p>For bromination, the equivalent initiation step is:<\/p>\n\n        <div class=\"ols-definition-box\">\n          <p><strong>Br<sub>2<\/sub> \u2192 2Br\u2022<\/strong><\/p>\n        <\/div>\n\n        <div class=\"ols-warning-box\">\n          <p><strong>Common mistake:<\/strong> Do not add charges to the radicals. Cl\u2022 and Br\u2022 are neutral radicals, not Cl<sup>&#8211;<\/sup> or Br<sup>&#8211;<\/sup> ions.<\/p>\n        <\/div>\n      <\/article>\n\n      <section class=\"ols-h5p-card\">\n        <h2>Check Your Understanding<\/h2>\n        <p>Use these short activities to check UV light, homolytic fission, radical formation and the correct initiation equations.<\/p>\n\n        <div class=\"ols-h5p-frame\"><div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-136\" class=\"h5p-iframe\" data-content-id=\"136\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"T4.7.2.1 Drag: Initiation Key Concepts\"><\/iframe><\/div><\/div>\n        <div class=\"ols-h5p-frame\"><div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-137\" class=\"h5p-iframe\" data-content-id=\"137\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"T4.7.2.2 MCQ: Role of UV Light in Initiation\"><\/iframe><\/div><\/div>\n        <div class=\"ols-h5p-frame\"><div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-138\" class=\"h5p-iframe\" data-content-id=\"138\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"T4.7.2.3 MCQ: Homolytic Fission in Initiation\"><\/iframe><\/div><\/div>\n        <div class=\"ols-h5p-frame\"><div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-139\" class=\"h5p-iframe\" data-content-id=\"139\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"T4.7.2.4 MCQ: Initiation Equations and Radical Notation\"><\/iframe><\/div><\/div>\n      <\/section>\n\n      <section class=\"ols-course-cta-topic6ab\" id=\"olsCourseCtaTopic6ab001\">\r\n  <style>\r\n    .ols-course-cta-topic6ab,\r\n    .ols-course-cta-topic6ab * {\r\n      box-sizing: border-box;\r\n    }\r\n\r\n    .ols-course-cta-topic6ab {\r\n      --navy: #1C244B;\r\n      --blue: #2563eb;\r\n      --body-text: #1f2937;\r\n      --grey-text: #667085;\r\n      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left: 12px;\r\n        bottom: 12px;\r\n        min-width: 84px;\r\n        padding: 9px 14px;\r\n        font-size: 13px;\r\n      }\r\n\r\n      .ols-course-cta-topic6ab .ols-course-button {\r\n        width: 100%;\r\n      }\r\n    }\r\n  <\/style>\r\n\r\n  <div class=\"ols-course-cta-card\">\r\n\r\n    <div class=\"ols-course-cta-top\">\r\n\r\n      <a class=\"ols-course-cta-image-link\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/product\/organic-chemistry-and-alkanes-topic-6ab\/\" aria-label=\"Open the Edexcel A Level Chemistry Topic 6A\/6B Organic Chemistry and Alkanes course page\">\r\n\r\n        <div class=\"ols-course-cta-image\">\r\n          <img decoding=\"async\"\r\n            src=\"https:\/\/www.onlinelearningsystem.net\/xyz\/wp-content\/uploads\/2026\/04\/edexcel-a-level-chemistry-topic-6a-6b-organic-chemistry-alkanes-course-banner.jpg\"\r\n            alt=\"Edexcel A Level Chemistry Topic 6A\/6B Organic Chemistry and Alkanes course banner\"\r\n          >\r\n        <\/div>\r\n\r\n      <\/a>\r\n\r\n      <div class=\"ols-course-cta-content\">\r\n\r\n        <div class=\"ols-course-cta-header-row\">\r\n\r\n          <div class=\"ols-course-cta-kicker\">\r\n            Complete Topic 6A\/6B Organic Chemistry & Alkanes Course\r\n          <\/div>\r\n\r\n          <a class=\"ols-course-button ols-course-button-top\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/product\/organic-chemistry-and-alkanes-topic-6ab\/\">\r\n            View Course\r\n          <\/a>\r\n\r\n        <\/div>\r\n\r\n        <h2>\r\n          Master Topic 6A\/6B Organic Chemistry and Alkanes for Edexcel A Level Chemistry\r\n        <\/h2>\r\n\r\n      <\/div>\r\n\r\n    <\/div>\r\n\r\n    <div class=\"ols-course-cta-intro-stats\">\r\n\r\n      <p class=\"ols-course-cta-intro\">\r\n        Continue from these free revision notes into the full Topic 6A\/6B Organic Chemistry and Alkanes course for Edexcel A Level Chemistry Paper 2 (9CH0\/02), with guided video teaching, diagnostic MCQ practice, teacher-marked short-answer questions and a specification assignment with a personalised progress report.\r\n      <\/p>\r\n\r\n      <div class=\"ols-course-cta-stats\">\r\n\r\n        <div class=\"ols-course-stat\">\r\n          <span>Exam paper<\/span>\r\n          <strong>Paper 2<\/strong>\r\n        <\/div>\r\n\r\n        <div class=\"ols-course-stat\">\r\n          <span>Course code<\/span>\r\n          <strong>9CH0\/02<\/strong>\r\n        <\/div>\r\n\r\n        <div class=\"ols-course-stat\">\r\n          <span>Guided learning<\/span>\r\n          <strong>16 hours<\/strong>\r\n        <\/div>\r\n\r\n        <div class=\"ols-course-stat\">\r\n          <span>Video lessons<\/span>\r\n          <strong>430 mins<\/strong>\r\n        <\/div>\r\n\r\n        <div class=\"ols-course-stat\">\r\n          <span>MCQ practice<\/span>\r\n          <strong>73 marks<\/strong>\r\n        <\/div>\r\n\r\n        <div class=\"ols-course-stat\">\r\n          <span>SAQ practice<\/span>\r\n          <strong>30 marks<\/strong>\r\n        <\/div>\r\n\r\n      <\/div>\r\n\r\n    <\/div>\r\n\r\n    <div class=\"ols-course-cta-features\">\r\n\r\n      <div class=\"ols-course-feature\">\r\n        <h3>Guided video teaching<\/h3>\r\n        <p>\r\n          Learn the chemistry and exam technique through structured video lessons with worked examples and walkthroughs.\r\n        <\/p>\r\n      <\/div>\r\n\r\n      <div class=\"ols-course-feature\">\r\n        <h3>Instant MCQ feedback<\/h3>\r\n        <p>\r\n          Auto-marked MCQ quizzes provide immediate diagnostic feedback for every answer choice.\r\n        <\/p>\r\n      <\/div>\r\n\r\n      <div class=\"ols-course-feature\">\r\n        <h3>Teacher-marked SAQs<\/h3>\r\n        <p>\r\n          Submit written exam responses and receive chemistry specialist feedback with improvement guidance.\r\n        <\/p>\r\n      <\/div>\r\n\r\n      <div class=\"ols-course-feature\">\r\n        <h3>Progress tracking<\/h3>\r\n        <p>\r\n          Identify strengths and weaknesses across the full Topic 6A\/6B specification with targeted reporting.\r\n        <\/p>\r\n      <\/div>\r\n\r\n    <\/div>\r\n\r\n    <div class=\"ols-course-animation-wrap\">\r\n\r\n      <h3 class=\"ols-course-animation-title\">\r\n        See how the course works\r\n      <\/h3>\r\n\r\n      <div class=\"ols-animation-frame-shell\">\r\n        <iframe\r\n          id=\"olsCourseAnimationFrameTopic6ab001\"\r\n          title=\"OLS course preview animation\"\r\n          loading=\"lazy\"\r\n          referrerpolicy=\"no-referrer\">\r\n        <\/iframe>\r\n\r\n        <button\r\n          class=\"ols-animation-start-overlay\"\r\n          id=\"olsCourseAnimationStartTopic6ab001\"\r\n          type=\"button\"\r\n          aria-label=\"Play OLS course preview animation\">\r\n          <span class=\"ols-animation-start-content\">\r\n            <span class=\"ols-animation-play-circle\" aria-hidden=\"true\">\r\n              <span class=\"ols-animation-play-icon\"><\/span>\r\n            <\/span>\r\n            <span class=\"ols-animation-start-text\">\r\n              Play course preview animation\r\n            <\/span>\r\n          <\/span>\r\n        <\/button>\r\n\r\n        <button\r\n          class=\"ols-animation-pause-button\"\r\n          id=\"olsCourseAnimationPauseTopic6ab001\"\r\n          type=\"button\"\r\n          aria-label=\"Pause course preview animation\">\r\n          Pause\r\n        <\/button>\r\n      <\/div>\r\n\r\n      <p class=\"ols-course-video-status\">\r\n        Click play to start the course preview animation.\r\n      <\/p>\r\n\r\n    <\/div>\r\n\r\n    <div class=\"ols-course-cta-bottom\">\r\n\r\n      <a class=\"ols-course-button\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/product\/organic-chemistry-and-alkanes-topic-6ab\/\">\r\n        View Organic Chemistry & Alkanes Topic 6A\/6B Course\r\n      <\/a>\r\n\r\n    <\/div>\r\n\r\n  <\/div>\r\n\r\n  <template id=\"olsCourseAnimationTemplateTopic6ab001\">\r\n<!DOCTYPE html>\r\n<html lang=\"en\">\r\n<head>\r\n<meta charset=\"UTF-8\">\r\n<meta name=\"viewport\" content=\"width=device-width, initial-scale=1.0\">\r\n<title>OLS Combined Promo Animation<\/title>\r\n\r\n<style>\r\n*{box-sizing:border-box;}\r\n\r\nhtml.ols-animation-paused *,\r\nhtml.ols-animation-paused *::before,\r\nhtml.ols-animation-paused *::after{\r\n  animation-play-state:paused!important;\r\n}\r\n\r\n:root{\r\n  --ols-video-screen-w:1180;\r\n  --ols-video-screen-h:664;\r\n  --ols-video-screen-scale:1;\r\n  --ols-mcq-screen-w:1360;\r\n  --ols-mcq-screen-h:1130;\r\n  --ols-mcq-screen-scale:1;\r\n  --ols-saq-screen-w:1360;\r\n  --ols-saq-screen-h:965;\r\n  --ols-saq-screen-scale:1;\r\n}\r\n\r\nhtml,\r\nbody{\r\n  width:100%;\r\n  height:100%;\r\n}\r\n\r\nbody{\r\n  margin:0;\r\n  overflow:hidden;\r\n  font-family:Poppins,Arial,sans-serif;\r\n  background:#e9efff;\r\n}\r\n\r\n.ols-combined-stage{\r\n  position:relative;\r\n  width:100vw;\r\n  height:100vh;\r\n  overflow:hidden;\r\n  background:\r\n    radial-gradient(circle at top left,rgba(70,127,247,0.14),transparent 34%),\r\n    linear-gradient(135deg,#f8fbff 0%,#e9efff 100%);\r\n}\r\n\r\n.ols-scene{\r\n  position:absolute;\r\n  inset:0;\r\n  width:100vw;\r\n  height:100vh;\r\n  opacity:0;\r\n  visibility:hidden;\r\n  pointer-events:none;\r\n}\r\n\r\n.ols-scene.active{\r\n  opacity:1;\r\n  visibility:visible;\r\n  pointer-events:auto;\r\n}\r\n\r\n.ols-scene.fade-out{\r\n  animation:olsSceneFadeOut 0.85s ease forwards;\r\n}\r\n\r\n@keyframes olsSceneFadeOut{\r\n  to{\r\n    opacity:0;\r\n    visibility:hidden;\r\n  }\r\n}\r\n\r\n.ols-title-cursor{\r\n  display:inline-block;\r\n  width:5px;\r\n  height:0.85em;\r\n  background:#1C244B;\r\n  margin-left:8px;\r\n  transform:translateY(8px);\r\n  animation:olsBlink 0.8s infinite;\r\n}\r\n\r\n.cursor{\r\n  display:inline-block;\r\n  width:3px;\r\n  height:28px;\r\n  background:#1c244b;\r\n  margin-left:3px;\r\n  transform:translateY(5px);\r\n  animation:olsBlink 0.8s infinite;\r\n}\r\n\r\n@keyframes olsBlink{\r\n  0%,45%{opacity:1;}\r\n  46%,100%{opacity:0;}\r\n}\r\n\r\n.ols-video-stage,\r\n.ols-mcq-stage,\r\n.ols-saq-stage{\r\n  width:100vw;\r\n  height:100vh;\r\n  display:flex;\r\n  justify-content:center;\r\n  align-items:center;\r\n  padding:0;\r\n  overflow:hidden;\r\n  background:\r\n    radial-gradient(circle at top left,rgba(70,127,247,0.14),transparent 34%),\r\n    linear-gradient(135deg,#f8fbff 0%,#e9efff 100%);\r\n}\r\n\r\n.ols-video-title-screen,\r\n.ols-mcq-intro-screen,\r\n.ols-saq-intro{\r\n  position:absolute;\r\n  inset:0;\r\n  z-index:50;\r\n  display:flex;\r\n  justify-content:center;\r\n  align-items:center;\r\n  background:\r\n    radial-gradient(circle at top left,rgba(70,127,247,0.14),transparent 34%),\r\n    linear-gradient(135deg,#f8fbff 0%,#e9efff 100%);\r\n  opacity:1;\r\n  visibility:visible;\r\n  pointer-events:none;\r\n}\r\n\r\n.ols-video-title-screen.hide{animation:olsVideoTitleFadeOut 0.85s ease forwards;}\r\n.ols-mcq-intro-screen.hide{animation:olsMcqIntroFadeOut 0.85s ease forwards;}\r\n.ols-saq-intro.hide{animation:olsSaqIntroFadeOut 0.85s ease forwards;}\r\n\r\n@keyframes olsVideoTitleFadeOut{to{opacity:0;visibility:hidden;}}\r\n@keyframes olsMcqIntroFadeOut{to{opacity:0;visibility:hidden;}}\r\n@keyframes olsSaqIntroFadeOut{to{opacity:0;visibility:hidden;}}\r\n\r\n.ols-video-title-wrap,\r\n.ols-mcq-intro-title-wrap,\r\n.ols-saq-intro-title-wrap{\r\n  max-width:1250px;\r\n  padding:0 34px;\r\n  text-align:center;\r\n}\r\n\r\n.ols-video-title,\r\n.ols-mcq-intro-title,\r\n.ols-saq-intro-title{\r\n  margin:0;\r\n  font-family:Poppins,Arial,sans-serif;\r\n  font-size:clamp(52px,8vw,124px);\r\n  font-weight:600;\r\n  line-height:1.08;\r\n  color:#1C244B;\r\n  text-shadow:-9px 0 9px rgba(28,36,75,0.16);\r\n  letter-spacing:-0.045em;\r\n}\r\n\r\n#videoTitleText,\r\n#mcqIntroTitleText,\r\n#saqIntroTitleText{\r\n  white-space:pre-wrap;\r\n}\r\n\r\n.ols-video-scene{\r\n  width:100%;\r\n  height:100%;\r\n  display:flex;\r\n  justify-content:center;\r\n  align-items:center;\r\n  opacity:0;\r\n  visibility:hidden;\r\n}\r\n\r\n.ols-video-scene.show{\r\n  visibility:visible;\r\n  animation:olsVideoSceneIn 1s ease forwards;\r\n}\r\n\r\n@keyframes olsVideoSceneIn{to{opacity:1;}}\r\n\r\n.ols-video-scale-wrap{\r\n  width:calc(var(--ols-video-screen-w) * 1px);\r\n  height:calc(var(--ols-video-screen-h) * 1px);\r\n  transform:scale(var(--ols-video-screen-scale));\r\n  transform-origin:center center;\r\n  display:flex;\r\n  justify-content:center;\r\n  align-items:center;\r\n}\r\n\r\n.ols-video-card{\r\n  width:1180px;\r\n  height:664px;\r\n  border-radius:28px;\r\n  overflow:hidden;\r\n  background:#1C244B;\r\n  box-shadow:0 28px 80px rgba(28,36,75,0.28);\r\n  transform:translateY(24px) scale(0.96);\r\n  opacity:0;\r\n}\r\n\r\n.ols-video-scene.show .ols-video-card{\r\n  animation:olsVideoCardIn 1s cubic-bezier(.18,.89,.32,1.12) forwards;\r\n  animation-delay:0.2s;\r\n}\r\n\r\n@keyframes olsVideoCardIn{\r\n  to{\r\n    transform:translateY(0) scale(1);\r\n    opacity:1;\r\n  }\r\n}\r\n\r\n.ols-video-card video{\r\n  display:block;\r\n  width:100%;\r\n  height:100%;\r\n  aspect-ratio:16 \/ 9;\r\n  object-fit:cover;\r\n  border:0;\r\n}\r\n\r\n.ols-mcq-scale-wrap,\r\n.ols-saq-scale-wrap{\r\n  width:calc(var(--ols-mcq-screen-w) * 1px);\r\n  height:calc(var(--ols-mcq-screen-h) * 1px);\r\n  transform:scale(var(--ols-mcq-screen-scale));\r\n  transform-origin:center center;\r\n  display:flex;\r\n  justify-content:center;\r\n  align-items:flex-start;\r\n}\r\n\r\n.ols-saq-scale-wrap{\r\n  width:calc(var(--ols-saq-screen-w) * 1px);\r\n  height:calc(var(--ols-saq-screen-h) * 1px);\r\n  transform:scale(var(--ols-saq-screen-scale));\r\n}\r\n\r\n.ols-mcq-screen{\r\n  width:1360px;\r\n  height:1130px;\r\n  border-radius:22px;\r\n  overflow:hidden;\r\n  background:#eaf0ff;\r\n  box-shadow:0 26px 70px rgba(28,36,75,0.22);\r\n  opacity:0;\r\n  transform:translateY(24px) scale(0.96);\r\n}\r\n\r\n.ols-mcq-screen.show{\r\n  animation:olsMcqScreenEnter 1s ease forwards;\r\n}\r\n\r\n@keyframes olsMcqScreenEnter{\r\n  from{opacity:0;transform:translateY(24px) scale(0.96);}\r\n  to{opacity:1;transform:translateY(0) scale(1);}\r\n}\r\n\r\n.mcq-question-area{\r\n  background:#eaf0ff;\r\n  padding:28px 30px 30px;\r\n  position:relative;\r\n  height:610px;\r\n}\r\n\r\n.mcq-question-lead{\r\n  margin:0 0 14px;\r\n  font-size:24px;\r\n  line-height:1.35;\r\n  color:#111827;\r\n}\r\n\r\n.mcq-ionic-table{\r\n  border-collapse:collapse;\r\n  width:500px;\r\n  margin-bottom:8px;\r\n  font-size:21px;\r\n  color:#111827;\r\n}\r\n\r\n.mcq-ionic-table th,\r\n.mcq-ionic-table td{\r\n  border:1.5px solid #c9ced8;\r\n  padding:12px 18px;\r\n  text-align:center;\r\n}\r\n\r\n.mcq-ionic-table th{\r\n  background:#f2f2f2;\r\n  font-weight:700;\r\n}\r\n\r\n.mcq-ionic-table td{\r\n  background:#eaf0ff;\r\n}\r\n\r\n.mcq-question-main{\r\n  margin:6px 0 28px;\r\n  font-size:24px;\r\n  line-height:1.35;\r\n  color:#111827;\r\n}\r\n\r\n.mcq-options-wrap{\r\n  display:flex;\r\n  flex-direction:column;\r\n  gap:17px;\r\n  max-width:1200px;\r\n}\r\n\r\n.mcq-option-row{\r\n  display:flex;\r\n  align-items:center;\r\n  min-height:34px;\r\n  position:relative;\r\n}\r\n\r\n.mcq-radio{\r\n  width:28px;\r\n  height:28px;\r\n  border-radius:50%;\r\n  border:2px solid #6b7280;\r\n  margin-right:16px;\r\n  background:transparent;\r\n  position:relative;\r\n  flex:0 0 auto;\r\n}\r\n\r\n.mcq-radio::after{\r\n  content:\"\";\r\n  position:absolute;\r\n  inset:5px;\r\n  border-radius:50%;\r\n  background:#6b7280;\r\n  opacity:0;\r\n  transform:scale(0.4);\r\n  transition:opacity 0.25s ease,transform 0.25s ease;\r\n}\r\n\r\n.mcq-option-row.selected .mcq-radio::after{\r\n  opacity:1;\r\n  transform:scale(1);\r\n}\r\n\r\n.mcq-radio-ripple{\r\n  position:absolute;\r\n  left:14px;\r\n  top:50%;\r\n  width:28px;\r\n  height:28px;\r\n  border-radius:50%;\r\n  border:2px solid rgba(28,36,75,0.28);\r\n  transform:translate(-50%,-50%) scale(1);\r\n  opacity:0;\r\n  pointer-events:none;\r\n}\r\n\r\n.mcq-option-row.clicking .mcq-radio-ripple{\r\n  animation:mcqRipple 0.75s ease forwards;\r\n}\r\n\r\n@keyframes mcqRipple{\r\n  0%{opacity:0.65;transform:translate(-50%,-50%) scale(1);}\r\n  100%{opacity:0;transform:translate(-50%,-50%) scale(2.5);}\r\n}\r\n\r\n.mcq-option-label{\r\n  font-size:23px;\r\n  color:#111827;\r\n}\r\n\r\n.mcq-specific-feedback{\r\n  display:inline-flex;\r\n  align-items:center;\r\n  margin-left:18px;\r\n  min-height:38px;\r\n  opacity:0;\r\n  transform:translateX(-8px);\r\n}\r\n\r\n.mcq-specific-feedback.show{\r\n  opacity:1;\r\n  transform:translateX(0);\r\n  transition:opacity 0.35s ease,transform 0.35s ease;\r\n}\r\n\r\n.mcq-cross-icon{\r\n  width:26px;\r\n  height:26px;\r\n  border-radius:50%;\r\n  border:2px solid #d83255;\r\n  color:#d83255;\r\n  display:inline-flex;\r\n  justify-content:center;\r\n  align-items:center;\r\n  font-size:18px;\r\n  font-weight:700;\r\n  margin-right:12px;\r\n  opacity:0;\r\n  transform:scale(0.4);\r\n}\r\n\r\n.mcq-cross-icon.show{\r\n  animation:mcqCrossPop 0.35s ease forwards;\r\n}\r\n\r\n@keyframes mcqCrossPop{\r\n  70%{opacity:1;transform:scale(1.18);}\r\n  100%{opacity:1;transform:scale(1);}\r\n}\r\n\r\n.mcq-specific-feedback-text{\r\n  display:inline-block;\r\n  background:#fff4b8;\r\n  color:#111827;\r\n  padding:8px 16px;\r\n  font-size:22px;\r\n  line-height:1.35;\r\n  min-width:850px;\r\n  min-height:44px;\r\n}\r\n\r\n.mcq-submit-button{\r\n  position:absolute;\r\n  right:34px;\r\n  bottom:30px;\r\n  border:0;\r\n  border-radius:999px;\r\n  background:#1C244B;\r\n  color:#ffffff;\r\n  padding:14px 28px;\r\n  font-size:18px;\r\n  font-weight:600;\r\n  box-shadow:0 14px 32px rgba(28,36,75,0.25);\r\n  cursor:default;\r\n  transition:transform 0.2s ease,box-shadow 0.2s ease,background 0.2s ease;\r\n}\r\n\r\n.mcq-submit-button.clicked{\r\n  transform:translateY(2px) scale(0.97);\r\n  background:#26315f;\r\n  box-shadow:0 7px 18px rgba(28,36,75,0.22);\r\n}\r\n\r\n.mcq-general-feedback{\r\n  height:520px;\r\n  background:#fff3c9;\r\n  color:#8a6a00;\r\n  padding:26px 30px 28px;\r\n  font-size:23px;\r\n  line-height:1.34;\r\n  opacity:0;\r\n  transform:translateY(20px);\r\n  transition:opacity 0.7s ease,transform 0.7s ease;\r\n  overflow:hidden;\r\n}\r\n\r\n.mcq-general-feedback.show{\r\n  opacity:1;\r\n  transform:translateY(0);\r\n}\r\n\r\n#mcqGeneralText{\r\n  white-space:pre-wrap;\r\n}\r\n\r\n.mcq-specific-cursor{background:#111827;}\r\n.mcq-general-cursor{background:#8a6a00;}\r\n\r\n.ols-saq-screen{\r\n  width:1360px;\r\n  height:965px;\r\n  border-radius:22px;\r\n  overflow:hidden;\r\n  background:#eaf0ff;\r\n  box-shadow:0 26px 70px rgba(28,36,75,0.22);\r\n  opacity:0;\r\n  transform:translateY(24px) scale(0.96);\r\n}\r\n\r\n.ols-saq-screen.show{\r\n  animation:olsSaqScreenEnter 1s ease forwards;\r\n}\r\n\r\n@keyframes olsSaqScreenEnter{\r\n  from{opacity:0;transform:translateY(24px) scale(0.96);}\r\n  to{opacity:1;transform:translateY(0) scale(1);}\r\n}\r\n\r\n.saq-question-area{\r\n  height:335px;\r\n  background:#eaf0ff;\r\n  padding:30px 40px 32px;\r\n}\r\n\r\n.saq-question-text{\r\n  font-size:25px;\r\n  line-height:1.42;\r\n  color:#111827;\r\n  margin-bottom:22px;\r\n}\r\n\r\n.saq-student-box{\r\n  height:195px;\r\n  background:#f3f4f6;\r\n  border:2px solid #cfd6e3;\r\n  border-radius:8px;\r\n  padding:23px 26px;\r\n  font-size:24px;\r\n  line-height:1.55;\r\n  color:#4b5563;\r\n  position:relative;\r\n  overflow:hidden;\r\n}\r\n\r\n.saq-teacher-feedback{\r\n  height:630px;\r\n  background:#dff3e6;\r\n  color:#075f3b;\r\n  padding:28px 40px 30px;\r\n  font-size:23px;\r\n  line-height:1.47;\r\n  opacity:0;\r\n  transform:translateY(20px);\r\n  transition:opacity 0.7s ease,transform 0.7s ease;\r\n  overflow:hidden;\r\n}\r\n\r\n.saq-teacher-feedback.show{\r\n  opacity:1;\r\n  transform:translateY(0);\r\n}\r\n\r\n#saqTeacherText{\r\n  white-space:pre-wrap;\r\n}\r\n\r\n.saq-teacher-cursor{\r\n  background:#075f3b;\r\n}\r\n\r\n@media(max-width:900px){\r\n  .ols-video-title,\r\n  .ols-mcq-intro-title,\r\n  .ols-saq-intro-title{\r\n    font-size:clamp(42px,11vw,78px);\r\n    line-height:1.12;\r\n  }\r\n\r\n  .ols-title-cursor{\r\n    width:4px;\r\n    margin-left:6px;\r\n  }\r\n\r\n  .ols-video-card{\r\n    border-radius:20px;\r\n  }\r\n}\r\n<\/style>\r\n<\/head>\r\n\r\n<body>\r\n<div class=\"ols-combined-stage\">\r\n\r\n  <section id=\"sceneVideo\" class=\"ols-scene active\">\r\n    <div class=\"ols-video-stage\">\r\n      <div id=\"videoTitleScreen\" class=\"ols-video-title-screen\">\r\n        <div class=\"ols-video-title-wrap\">\r\n          <h1 class=\"ols-video-title\">\r\n            <span id=\"videoTitleText\"><\/span><span id=\"videoTitleCursor\" class=\"ols-title-cursor\"><\/span>\r\n          <\/h1>\r\n        <\/div>\r\n      <\/div>\r\n\r\n      <section id=\"videoScene\" class=\"ols-video-scene\">\r\n        <div class=\"ols-video-scale-wrap\">\r\n          <div class=\"ols-video-card\">\r\n            <video\r\n              id=\"lessonVideo\"\r\n              src=\"https:\/\/www.onlinelearningsystem.net\/xyz\/wp-content\/uploads\/2026\/05\/Virtual-Lesson.mp4\"\r\n              muted\r\n              playsinline\r\n              preload=\"auto\">\r\n            <\/video>\r\n          <\/div>\r\n        <\/div>\r\n      <\/section>\r\n    <\/div>\r\n  <\/section>\r\n\r\n  <section id=\"sceneMcq\" class=\"ols-scene\">\r\n    <div class=\"ols-mcq-stage\">\r\n      <div id=\"mcqIntroScreen\" class=\"ols-mcq-intro-screen\">\r\n        <div class=\"ols-mcq-intro-title-wrap\">\r\n          <h1 class=\"ols-mcq-intro-title\">\r\n            <span id=\"mcqIntroTitleText\"><\/span><span id=\"mcqIntroTitleCursor\" class=\"ols-title-cursor\"><\/span>\r\n          <\/h1>\r\n        <\/div>\r\n      <\/div>\r\n\r\n      <div class=\"ols-mcq-scale-wrap\">\r\n        <main id=\"mcqScreen\" class=\"ols-mcq-screen\">\r\n          <section class=\"mcq-question-area\">\r\n            <p class=\"mcq-question-lead\">Some ionic radii are shown.<\/p>\r\n\r\n            <table class=\"mcq-ionic-table\">\r\n              <thead>\r\n                <tr>\r\n                  <th>Ion<\/th>\r\n                  <th>Ionic radius \/ nm<\/th>\r\n                <\/tr>\r\n              <\/thead>\r\n              <tbody>\r\n                <tr><td>Na<sup>+<\/sup><\/td><td>0.102<\/td><\/tr>\r\n                <tr><td>K<sup>+<\/sup><\/td><td>0.138<\/td><\/tr>\r\n                <tr><td>F<sup>\u2212<\/sup><\/td><td>0.133<\/td><\/tr>\r\n                <tr><td>Cl<sup>\u2212<\/sup><\/td><td>0.180<\/td><\/tr>\r\n              <\/tbody>\r\n            <\/table>\r\n\r\n            <p class=\"mcq-question-main\">Which compound has the strongest ionic bonding?<\/p>\r\n\r\n            <div class=\"mcq-options-wrap\">\r\n              <div id=\"mcqWrongOption\" class=\"mcq-option-row\">\r\n                <span class=\"mcq-radio\"><\/span>\r\n                <span class=\"mcq-radio-ripple\"><\/span>\r\n                <span class=\"mcq-option-label\">sodium chloride<\/span>\r\n\r\n                <span id=\"mcqSpecificFeedback\" class=\"mcq-specific-feedback\">\r\n                  <span id=\"mcqCrossIcon\" class=\"mcq-cross-icon\">\u00d7<\/span>\r\n                  <span class=\"mcq-specific-feedback-text\">\r\n                    <span id=\"mcqSpecificText\"><\/span><span id=\"mcqSpecificCursor\" class=\"cursor mcq-specific-cursor\" style=\"display:none;\"><\/span>\r\n                  <\/span>\r\n                <\/span>\r\n              <\/div>\r\n\r\n              <div class=\"mcq-option-row\"><span class=\"mcq-radio\"><\/span><span class=\"mcq-radio-ripple\"><\/span><span class=\"mcq-option-label\">potassium chloride<\/span><\/div>\r\n              <div class=\"mcq-option-row\"><span class=\"mcq-radio\"><\/span><span class=\"mcq-radio-ripple\"><\/span><span class=\"mcq-option-label\">sodium fluoride<\/span><\/div>\r\n              <div class=\"mcq-option-row\"><span class=\"mcq-radio\"><\/span><span class=\"mcq-radio-ripple\"><\/span><span class=\"mcq-option-label\">potassium fluoride<\/span><\/div>\r\n            <\/div>\r\n\r\n            <button id=\"mcqSubmitButton\" class=\"mcq-submit-button\">Submit answer<\/button>\r\n          <\/section>\r\n\r\n          <section id=\"mcqGeneralFeedback\" class=\"mcq-general-feedback\">\r\n            <span id=\"mcqGeneralText\"><\/span><span id=\"mcqGeneralCursor\" class=\"cursor mcq-general-cursor\" style=\"display:none;\"><\/span>\r\n          <\/section>\r\n        <\/main>\r\n      <\/div>\r\n    <\/div>\r\n  <\/section>\r\n\r\n  <section id=\"sceneSaq\" class=\"ols-scene\">\r\n    <div class=\"ols-saq-stage\">\r\n      <div id=\"saqIntro\" class=\"ols-saq-intro\">\r\n        <div class=\"ols-saq-intro-title-wrap\">\r\n          <h1 class=\"ols-saq-intro-title\">\r\n            <span id=\"saqIntroTitleText\"><\/span><span id=\"saqIntroTitleCursor\" class=\"ols-title-cursor\"><\/span>\r\n          <\/h1>\r\n        <\/div>\r\n      <\/div>\r\n\r\n      <div class=\"ols-saq-scale-wrap\">\r\n        <main id=\"saqScreen\" class=\"ols-saq-screen\">\r\n          <section class=\"saq-question-area\">\r\n            <div class=\"saq-question-text\">\r\n              <strong>(ii)<\/strong>&nbsp;&nbsp; Melting temperature depends on the strength of metallic bonding.<br>\r\n              Explain why the metallic bonding in magnesium is much stronger than that in sodium.\r\n            <\/div>\r\n\r\n            <div class=\"saq-student-box\">\r\n              <span id=\"saqStudentText\"><\/span><span 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compound has the strongest ionic bonding, recall the key principle:\\n\\n\"+\r\n\"\u2022 Ionic bond strength increases when ionic radii are small, because the ions can get closer together.\\n\"+\r\n\"\u2022 Smaller ions \u2192 stronger electrostatic attraction \u2192 stronger ionic lattice.\\n\"+\r\n\"\u2022 Na\u207a (0.102 nm) is smaller than K\u207a (0.138 nm).\\n\"+\r\n\"\u2022 F\u207b (0.133 nm) is smaller than Cl\u207b (0.180 nm).\\n\\n\"+\r\n\"Therefore, the strongest ionic bonding occurs in the compound formed by the smallest cation and the smallest anion \u2192 sodium fluoride (NaF).\\n\\n\"+\r\n\"The correct answer is: sodium fluoride\";\r\n\r\nconst mcqIntroScreen=document.getElementById(\"mcqIntroScreen\");\r\nconst mcqIntroTitleText=document.getElementById(\"mcqIntroTitleText\");\r\nconst mcqIntroTitleCursor=document.getElementById(\"mcqIntroTitleCursor\");\r\nconst mcqScreen=document.getElementById(\"mcqScreen\");\r\nconst 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Melting temperature is a result of bonding strength, not the cause of it.\\n\\n\"+\r\n\"In metallic bonding, positive metal ions are attracted to a sea of delocalised electrons. The strength of this attraction depends on the charge of the ions and the number of delocalised electrons.\\n\\n\"+\r\n\"Magnesium forms Mg\u00b2\u207a ions and contributes two delocalised electrons per atom, whereas sodium forms Na\u207a ions and contributes only one electron. This results in a stronger electrostatic attraction in magnesium. Additionally, Mg\u00b2\u207a ions have a higher charge density than Na\u207a ions, further strengthening the metallic bonding.\\n\\n\"+\r\n\"Next time, include:\\n\"+\r\n\"\u2022 Ion charge: magnesium forms Mg\u00b2\u207a, sodium forms Na\u207a \u2713\\n\"+\r\n\"\u2022 Delocalised electrons: magnesium provides more electrons to the sea \u2713\\n\"+\r\n\"\u2022 Charge density: smaller, more highly charged ions create stronger attraction \u2713\\n\\n\"+\r\n\"You were close. 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UV light breaks a halogen-halogen bond by homolytic fission, forming halogen free radicals.<\/p>\n          <\/div>\n\n          <div class=\"ols-faq-item\">\n            <h3>What condition is needed for initiation?<\/h3>\n            <p>Ultraviolet light is needed. It provides enough energy to break the Cl-Cl or Br-Br bond and produce radicals.<\/p>\n          <\/div>\n\n          <div class=\"ols-faq-item\">\n            <h3>What is homolytic fission?<\/h3>\n            <p>Homolytic fission is bond breaking where each atom takes one electron from the shared covalent bond. This forms free radicals.<\/p>\n          <\/div>\n\n          <div class=\"ols-faq-item\">\n            <h3>Why does UV light break Cl-Cl rather than C-H?<\/h3>\n            <p>The Cl-Cl bond is weaker than the C-H bond, so UV light breaks the chlorine-chlorine bond preferentially during initiation.<\/p>\n          <\/div>\n\n          <div class=\"ols-faq-item\">\n            <h3>How are free radicals shown in equations?<\/h3>\n            <p>Free radicals are shown using a dot to represent an unpaired electron, for example Cl\u2022 or Br\u2022.<\/p>\n          <\/div>\n        <\/div>\n      <\/section>\n\n      <section class=\"ols-related-card\">\n        <h2>Related Topics<\/h2>\n        <p>Use these linked revision notes to build the full free-radical substitution mechanism.<\/p>\n\n        <div class=\"ols-related-grid\">\n          <a class=\"ols-related-item\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/free-radical-substitution\/\">Free Radical Substitution<\/a>\n          <a class=\"ols-related-item\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/propagation\/\">Propagation<\/a>\n          <a class=\"ols-related-item\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/termination\/\">Termination<\/a>\n          <a class=\"ols-related-item\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/further-substitution\/\">Further Substitution<\/a>\n          <a class=\"ols-related-item\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/fuel\/combustion\/\">Combustion<\/a>\n          <a class=\"ols-related-item\" href=\"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkenes\/\">Alkenes<\/a>\n        <\/div>\n      <\/section>\n\n      \n\n      <!-- OLS Author Copyright Footprint \/ Attribution Card -->\n      <section class=\"ols-attribution-card\">\n        <style>\n          .ols-attribution-card {\n            background: linear-gradient(135deg, #ffffff, #f8fbff);\n            border: 1px solid rgba(28, 36, 75, 0.14);\n            border-radius: 28px;\n            box-shadow: 0 18px 45px rgba(28, 36, 75, 0.10);\n            padding: 34px;\n            margin-bottom: 24px;\n            overflow: hidden;\n            font-family: Poppins, Arial, sans-serif;\n            box-sizing: border-box;\n          }\n\n          .ols-attribution-card,\n          .ols-attribution-card * {\n            box-sizing: border-box;\n          }\n\n          .ols-attribution-card p {\n            margin: 0;\n            font-size: 14px;\n            line-height: 1.65;\n            font-weight: 300;\n            color: #667085;\n          }\n\n          .ols-attribution-card strong {\n            font-weight: 700;\n            color: #1C244B;\n          }\n\n          @media (max-width: 760px) {\n            .ols-attribution-card {\n              padding: 24px 18px;\n              border-radius: 22px;\n            }\n          }\n        <\/style>\n\n        <p><strong>Copyright notice:<\/strong> This OLS revision content, including the explanations, layout, diagrams, tables and embedded learning structure, is authored for Online Learning System by Dr. Mohammed Al-Fatah. It may not be copied, reproduced, redistributed or adapted without written permission.<\/p>\n      <\/section>\n\n      <script type=\"application\/ld+json\">\n{\n        \"@context\": \"https:\/\/schema.org\",\n        \"@graph\": [\n                {\n                        \"@type\": \"WebPage\",\n                        \"@id\": \"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/initiation\/#webpage\",\n                        \"url\": \"https:\/\/www.onlinelearningsystem.net\/xyz\/revision-notes\/a-level-chemistry\/edexcel\/topic-6-organic-chemistry-i\/alkanes\/reactions\/initiation\/\",\n                        \"name\": \"Initiation - Edexcel A Level Chemistry Revision Notes\",\n                        \"description\": \"Edexcel Edexcel A Level Chemistry revision notes explaining the initiation step in free radical substitution, including UV light, homolytic fission, chlorine and bromine 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