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Edexcel A Level Chemistry

Topic 2
Bonding
and Structure

Topic 2 explains how particles are held together and how bonding affects structure and physical properties. This topic covers ionic bonding, covalent bonding, molecular shapes, electronegativity, polarity, intermolecular forces, solvent choice, metallic bonding and the relationship between structure and behaviour.

Exam Papers
Paper 1 & 2
9CH0/01 and 9CH0/02
Specification Points
2.1 – 2.27
27 points covered
Sub-topics
7 lessons
Revision notes available
Exam Board
Edexcel
Pearson 9CH0

Revision Notes

7 revision notes, in the order the specification teaches them.

A cube lattice of alternating large and small ions
1

Ionic Bonding

Ion formation, dot-and-cross diagrams, ionic lattices, ionic radius, ionic charge, ion migration and physical properties.

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Two overlapping atoms sharing a pair of electrons
2

Covalent Bonding

Covalent attraction, dot-and-cross diagrams, bond length, bond strength and dative covalent bonding.

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A ball-and-stick molecule with six atoms around a centre
3

Shapes of Molecules

Electron-pair repulsion theory, bond angles and predicting the shapes of molecules and ions.

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A polar bent molecule beside a symmetrical non-polar molecule
4

Polar Molecules

Electronegativity, polar bonds, non-polar molecules and using molecular symmetry to predict overall polarity.

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Rows of metal ions in a sea of electrons
5

Metallic Bonding

Giant metallic lattices, metal ions, delocalised electrons, electrical conductivity and melting temperature.

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Molecules held together by forces between them
6

Intermolecular Forces

London forces, permanent dipole-dipole forces, hydrogen bonding and boiling temperature trends.

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Separate small molecules beside one giant network
7

Structure Types

Giant ionic, giant covalent, giant metallic and simple molecular structures linked to physical properties.

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Summary Map

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Summary map

Download, print and revise the key facts of this topic at a glance.

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Summary map · PDF

Structure Types Map

Edexcel A Level Chemistry · Topic 2 Bonding and Structure · Structure Types

The whole section on one A4 page: diamond, graphite and graphene, the four kinds of solid lattice, and how to deduce a structure from its properties.

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Virtual Lessons

Recorded video lessons that teach the topic step by step.

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Virtual Lessons

Taught step by step in 2 recorded video lessons, to watch at your own pace.

Topic 2A Ionic Bonding taught by a specialist chemistry teacher, in 2 recorded video lessons that follow the specification.

  • Learn it before you revise itEach lesson explains the chemistry step by step, with the diagrams, mechanisms and worked examples the exam expects.
  • At your own pacePause, rewind and rewatch any part. Each lesson opens where you stopped.
  • Your progress is keptA lesson is ticked off once you have watched most of it, here and in your course on Moodle.

MCQ Bank

Multiple-choice papers on this topic, marked the moment you submit. MCQ (A) is free.

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Test yourself: 4 MCQ papers

Exam-style multiple-choice papers, marked the moment you submit with every answer explained. MCQ (A) is free.

4 exam-style multiple-choice papers, MCQ (A) to (D): 77 questions on Topic 2A Ionic Bonding, written the way the exam asks them.

  • Marked the moment you submitYour score straight away, with every answer explained, right or wrong.
  • Revise what you missedEach explanation links to the revision notes for that point.
  • MCQ (A) is freeTry the first paper now. MCQ (B) to (D) come with the course.
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SAQ Bank

Written, drawn and worked exam practice on this topic, marked by a specialist chemistry teacher.

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Written and drawn answers: 3 papers

Draw, write and calculate the way the exam asks, then a specialist chemistry teacher marks your work.

3 exam papers, (A) to (C): 39 questions on Topic 2A Ionic Bonding with no multiple choice. You write explanations, work out calculations and draw answers: structures, mechanisms and diagrams.

  • Answer the way the exam asksThe real paper wants written, worked and drawn answers, so that is how you practise.
  • Marked by a teacher, assisted by KASPA specialist chemistry teacher marks every answer against the mark scheme, with feedback on what to fix.
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Study Cards

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Specification

Every specification point in this topic, in the exam board's own words. Rate how confident you are with each one.

Official Pearson Edexcel documentsSpecification (opens the Pearson Edexcel website in a new tab)Data booklet (opens the Pearson Edexcel website in a new tab)

Self-assessment · 69 points

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2

  1. A.1

    know that ionic bonding is the strong electrostatic attraction between oppositely charged ions

    Revise
  2. A.2 a

    understand the effect of ionic radius on the strength of ionic bonding

    Revise
  3. A.2 b

    understand the effect of ionic charge on the strength of ionic bonding

    Revise
  4. A.3 a

    understand the formation of cations in terms of electron loss

    Revise
  5. A.3 b

    understand the formation of anions in terms of electron gain

    Revise
  6. A.4 a

    be able to draw electronic configuration diagrams of cations using dot-and-cross diagrams

    Revise
  7. A.4 b

    be able to draw electronic configuration diagrams of anions using dot-and-cross diagrams

    Revise
  8. A.5 a

    understand reasons for trends in ionic radii down a group

    Revise
  9. A.5 b

    understand reasons for trends in ionic radii for a set of isoelectronic ions such as N3- to Al3+

    Revise
  10. A.6 a

    understand that physical properties of ionic compounds provide evidence for the existence of ions

    Revise
  11. A.6 b

    understand that migration of ions provides evidence for the existence of ions

    Revise
  12. A.7

    know that a covalent bond is the strong electrostatic attraction between two nuclei and the shared pair of electrons between them

    Revise
  13. A.8i

    be able to draw dot-and-cross diagrams to show electrons in covalent substances, including: molecules with single, double and triple bonds

    Revise
  14. A.8ii

    be able to draw dot-and-cross diagrams to show electrons in covalent substances, including: species exhibiting dative covalent (coordinate) bonding, including Al2Cl6 and ammonium ion

    Revise
  15. A.9

    understand the relationship between bond lengths and covalent bond strengths

    Revise
  16. A.10 a

    understand that the shape of a simple molecule is determined by repulsion between electron pairs around a central atom

    Revise
  17. A.10 b

    understand that the shape of a simple ion is determined by repulsion between electron pairs around a central atom

    Revise
  18. A.11 a

    understand reasons for the shape of, and bond angles in, BeCl2

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  19. A.11 b

    understand reasons for the shape of, and bond angles in, BCl3

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  20. A.11 c

    understand reasons for the shape of, and bond angles in, CH4

    Revise
  21. A.11 d

    understand reasons for the shape of, and bond angles in, NH3

    Revise
  22. A.11 e

    understand reasons for the shape of, and bond angles in, NH4+

    Revise
  23. A.11 f

    understand reasons for the shape of, and bond angles in, H2O

    Revise
  24. A.11 g

    understand reasons for the shape of, and bond angles in, CO2

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  25. A.11 h

    understand reasons for the shape of, and bond angles in, PCl5(g)

    Revise
  26. A.11 i

    understand reasons for the shape of, and bond angles in, SF6(g)

    Revise
  27. A.11 j

    understand reasons for the shape of, and bond angles in, related molecules and ions

    Revise
  28. A.11 k

    understand reasons for the shape of, and bond angles in, simple organic molecules in this specification

  29. A.12 a

    be able to predict the shapes of simple molecules analogous to specified examples using electron-pair repulsion theory

    Revise
  30. A.12 b

    be able to predict the bond angles in simple molecules analogous to specified examples using electron-pair repulsion theory

    Revise
  31. A.12 c

    be able to predict the shapes of simple ions analogous to specified examples using electron-pair repulsion theory

    Revise
  32. A.12 d

    be able to predict the bond angles in simple ions analogous to specified examples using electron-pair repulsion theory

    Revise
  33. A.13

    know that electronegativity is the ability of an atom to attract the bonding electrons in a covalent bond

    Revise
  34. A.14 a

    know that ionic and covalent bonding are the extremes of a continuum of bonding type

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  35. A.14 b

    know that electronegativity differences lead to bond polarity in bonds

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  36. A.14 c

    know that electronegativity differences lead to bond polarity in molecules

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  37. A.15 a

    understand that molecules with polar bonds may not be polar molecules

    Revise
  38. A.15 b

    be able to predict whether or not a given molecule is likely to be polar

    Revise
  39. A.16i

    understand the nature of intermolecular forces resulting from the following interactions: London forces (instantaneous dipole – induced dipole)

    Revise
  40. A.16ii

    understand the nature of intermolecular forces resulting from the following interactions: permanent dipoles

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  41. A.16iii

    understand the nature of intermolecular forces resulting from the following interactions: hydrogen bonds

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  42. A.17 a

    understand interactions in H2O that give rise to hydrogen bonding

    Revise
  43. A.17 b

    understand interactions in liquid NH3 that give rise to hydrogen bonding

    Revise
  44. A.17 c

    understand interactions in liquid HF that give rise to hydrogen bonding

    Revise
  45. A.18i

    understand the following anomalous properties of water resulting from hydrogen bonding: its relatively high melting temperature and boiling temperature

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  46. A.18ii

    understand the following anomalous properties of water resulting from hydrogen bonding: the density of ice compared to that of water

    Revise
  47. A.19

    be able to predict the presence of hydrogen bonding in molecules analogous to those mentioned above

    Revise
  48. A.20i

    understand, in terms of intermolecular forces, physical properties shown by materials, including: the trends in boiling temperatures of alkanes with increasing chain length

    Revise
  49. A.20ii

    understand, in terms of intermolecular forces, physical properties shown by materials, including: the effect of branching in the carbon chain on the boiling temperatures of alkanes

    Revise
  50. A.20iii

    understand, in terms of intermolecular forces, physical properties shown by materials, including: the relatively low volatility (higher boiling temperatures) of alcohols compared to alkanes with a similar number of electrons

    Revise
  51. A.20iv

    understand, in terms of intermolecular forces, physical properties shown by materials, including: the trends in boiling temperatures of the hydrogen halides, HF to HI

    Revise
  52. A.21i

    understand factors that influence the choice of solvents, including: water, to dissolve some ionic compounds, in terms of the hydration of the ions

    Revise
  53. A.21ii

    understand factors that influence the choice of solvents, including: water, to dissolve simple alcohols, in terms of hydrogen bonding

    Revise
  54. A.21iii

    understand factors that influence the choice of solvents, including: water, as a poor solvent for compounds (to include polar molecules such as halogenoalkanes), in terms of inability to form hydrogen bonds

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  55. A.21iv

    understand factors that influence the choice of solvents, including: non-aqueous solvents, for compounds that have similar intermolecular forces to those in the solvent

    Revise
  56. A.22

    know that metallic bonding is the strong electrostatic attraction between metal ions and the delocalised electrons

    Revise
  57. B.23i

    know that giant lattices are present in: ionic solids (giant ionic lattices)

    Revise
  58. B.23ii

    know that giant lattices are present in: covalently bonded solids, such as diamond, graphite and silicon(IV) oxide (giant covalent lattices)

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  59. B.23iii

    know that giant lattices are present in: solid metals (giant metallic lattices)

    Revise
  60. B.24 a

    know that iodine, I2, has a simple molecular structure

    Revise
  61. B.24 b

    know that ice, H2O, has a simple molecular structure

    Revise
  62. B.25 a

    know the structure of graphite

    Revise
  63. B.25 b

    know the structure of diamond

    Revise
  64. B.25 c

    know the structure of graphene

    Revise
  65. B.26 a

    be able to predict the type of structure present in a substance from numerical data and/or other information

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  66. B.26 b

    be able to predict the type of bonding present in a substance from numerical data and/or other information

    Revise
  67. B.27i

    be able to predict the physical properties of a substance, including melting and boiling temperature, electrical conductivity and solubility in water, in terms of: the types of particle present (atoms, molecules, ions, electrons)

    Revise
  68. B.27ii

    be able to predict the physical properties of a substance, including melting and boiling temperature, electrical conductivity and solubility in water, in terms of: the structure of the substance

    Revise
  69. B.27iii

    be able to predict the physical properties of a substance, including melting and boiling temperature, electrical conductivity and solubility in water, in terms of: the type of bonding and the presence of intermolecular forces, where relevant

    Revise