3.2.1
Enthalpy Changes
Section 3.2.1 covers enthalpy changes: exothermic and endothermic reactions, enthalpy profile diagrams and activation energy, standard conditions and standard states, the enthalpy changes of reaction, formation, combustion and neutralisation, determining enthalpy changes from q = mcΔT, average bond enthalpies, and Hess’ law cycles using combustion, formation and unfamiliar data.
Revision Notes
5 revision notes, in the order the specification teaches them.
Enthalpy Changes and Standard Conditions
Exothermic and endothermic reactions, enthalpy profile diagrams, activation energy and standard conditions.
Start revisingStandard Enthalpy Changes
The standard enthalpy change definitions and the equation each one refers to.
Start revisingCalorimetry: Measuring Enthalpy Changes
Calculating ΔH from a temperature change, cooling curve corrections, errors and assumptions.
Start revisingHess’s Law and Enthalpy Cycles
Building enthalpy cycles and calculating ΔH from formation and combustion data.
Start revisingBond Enthalpies
Average bond enthalpy, calculating ΔH from bonds broken and made, and why the answers differ from Hess values.
Start revisingSummary Map
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Enthalpy Profiles and Definitions Map
OCR A Level Chemistry A · 3.2.1 Enthalpy changes: Enthalpy profiles and definitions
The whole section on one A4 page: ΔH and its sign, enthalpy profiles and Eₐ, standard conditions and the standard enthalpy changes.
Calorimetry Map
OCR A Level Chemistry A · 3.2.1 Enthalpy changes: Calorimetry
The whole section on one A4 page: q = mcΔT, reactions in solution, burning fuels, errors and assumptions, uncertainty and the cooling-curve correction.
Hess's Law Map
OCR A Level Chemistry A · 3.2.1 Enthalpy changes: Hess's law
The whole section on one A4 page: Hess's law, formation and combustion cycles, combining equations, PAG 3 and evaluating the result.
Bond Enthalpies Map
OCR A Level Chemistry A · 3.2.1 Enthalpy changes: Bond enthalpies
The whole section on one A4 page: bond enthalpy, average bond enthalpy, ΔH from bonds broken and made, working back, limitations and which bond breaks first.
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3.2.1
- a i
explanation that some chemical reactions are accompanied by enthalpy changes that are exothermic (ΔH, negative)
Revise - a ii
explanation that some chemical reactions are accompanied by enthalpy changes that are endothermic (ΔH, positive)
Revise - b
construction of enthalpy profile diagrams to show the difference in the enthalpy of reactants compared with products
Revise - c
qualitative explanation of the term activation energy, including use of enthalpy profile diagrams
Revise - d (i) b
explanation and use of the term standard states (physical states under standard conditions)
Revise - d (ii)
explanation and use of the term enthalpy change of reaction (enthalpy change associated with a stated equation, ΔrH)
Revise - d (iii)
explanation and use of the term enthalpy change of formation (formation of 1 mol of a compound from its elements, ΔfH)
Revise - d (iv)
explanation and use of the term enthalpy change of combustion (complete combustion of 1 mol of a substance, ΔcH)
Revise - d (v)
explanation and use of the term enthalpy change of neutralisation (formation of 1 mol of water from neutralisation, ΔneutH)
Revise - e
determination of enthalpy changes directly from appropriate experimental results, including use of the relationship: q = mcΔT
Revise - f (i)
explanation of the term average bond enthalpy (as the breaking of 1 mol of bonds in gaseous molecules)
Revise - f (ii) a
explanation of exothermic reactions in terms of enthalpy changes associated with the breaking and making of chemical bonds
Revise - f (ii) b
explanation of endothermic reactions in terms of enthalpy changes associated with the breaking and making of chemical bonds
Revise - f (iii)
use of average bond enthalpies to calculate enthalpy changes and related quantities (see also 2.2.2 f)
Revise - g (i)
Hess' law for construction of enthalpy cycles and calculations to determine indirectly an enthalpy change of reaction from enthalpy changes of combustion
Revise - g (ii)
Hess' law for construction of enthalpy cycles and calculations to determine indirectly an enthalpy change of reaction from enthalpy changes of formation
Revise - g (iii)
Hess' law for construction of enthalpy cycles and calculations to determine indirectly enthalpy changes from unfamiliar enthalpy cycles
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