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AQA A Level Chemistry

3.3.7
Optical
Isomerism

Section 3.3.7 covers optical isomerism as a form of stereoisomerism: an asymmetric carbon atom is chiral and gives rise to enantiomers, which are non-superimposable mirror images that differ in their effect on plane polarised light; a racemic mixture (racemate) contains equal amounts of the two enantiomers; and the structural and displayed formulas of enantiomers are drawn.

Exam Paper
Paper 2
7405/2 (and Paper 3)
Specification Points
3.3.7
1 section covered
Sub-topics
2 lessons
Revision notes available
Exam Board
AQA
7405 (2015 onwards)

Revision Notes

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Optical Isomerism Map

AQA A-level Chemistry · 3.3.7 Optical isomerism

The whole section on one A4 page: chiral centres, enantiomers, drawing in 3D, plane-polarised light, racemic mixtures and where racemates come from.

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3.3.7

  1. i

    know that optical isomerism is a form of stereoisomerism arising from chirality, limited to molecules with a single chiral centre

    Revise
  2. ii a

    know that an asymmetric carbon atom is chiral

    Revise
  3. ii b

    know that chiral asymmetric carbon atoms give rise to optical isomers (enantiomers)

    Revise
  4. ii c

    know that enantiomers exist as non-superimposable mirror images

    Revise
  5. ii d

    know that enantiomers differ in their effect on plane polarised light

    Revise
  6. iii

    know that a mixture of equal amounts of enantiomers is called a racemic mixture (racemate)

    Revise
  7. iv

    draw the structural formulas and displayed formulas of enantiomers

    Revise
  8. v

    understand how racemic mixtures are formed and why they are optically inactive

    Revise