Shapes of Molecules
Molecular shape depends on the number of bonding pairs and lone pairs around a central atom. These pages separate the key geometries so that students can revise electron-pair repulsion, bond angles and how lone pairs change the final shape.
The section also covers ionic and metallic bonding, simple molecular and giant lattices, and intermolecular forces with hydrogen bonding and the anomalous properties of water.
Revision Notes
11 revision notes, in the order the specification teaches them.
Linear
Revise linear molecules with two bonding regions around the central atom and a bond angle of 180°.
Start revisingTrigonal Planar
Learn trigonal planar geometry, where three bonding regions arrange at 120° around the central atom.
Start revisingTetrahedral
Revise tetrahedral molecules with four bonding pairs and bond angles of about 109.5°.
Start revisingTrigonal Pyramidal
Understand how one lone pair changes a tetrahedral electron-pair arrangement into a trigonal pyramidal shape.
Start revisingBent
Learn how lone pairs compress bond angles and produce bent or V-shaped molecules such as H₂O.
Start revisingTrigonal Bipyramidal
Revise five-region electron-pair geometry with axial and equatorial positions.
Start revisingOctahedral
Learn octahedral geometry, where six bonding regions arrange at 90° around the central atom.
Start revisingSquare Planar
Revise square planar shapes formed from octahedral electron-pair arrangements with two opposite lone pairs.
Start revisingSquare Pyramidal
Understand square pyramidal molecules and how one lone pair affects an octahedral arrangement.
Start revisingDistorted T
Learn distorted T-shaped molecules where lone pairs alter the arrangement of bonding pairs around the central atom.
Start revisingSeeSaw
Revise seesaw shapes formed from trigonal bipyramidal electron-pair arrangements with one lone pair.
Start revisingSummary Map
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Summary map
Download, print and revise the key facts of this topic at a glance.
Shapes of Molecules Map
OCR A Level Chemistry A · 2.2.2 Bonding and structure · Shapes of molecules
The whole section on one A4 page: electron-pair repulsion, lone pairs, five and six pairs, related species and polar molecules.
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Specification
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2.2.2
- g i
the shapes of molecules and ions with up to six electron pairs (including lone pairs) surrounding the central atom as predicted by electron pair repulsion
Revise - g ii
the bond angles in molecules and ions with up to six electron pairs (including lone pairs) surrounding the central atom as predicted by electron pair repulsion
Revise
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