3.2.3
Chemical
Equilibrium
Section 3.2.3 covers dynamic equilibrium in a closed system, le Chatelier’s principle for temperature, pressure and concentration, why a catalyst leaves the position of equilibrium unchanged, the techniques used to investigate equilibria, the industrial compromise between equilibrium and rate, and the equilibrium constant Kc: expressions, calculations from equilibrium concentrations and estimating the position of equilibrium from its size.
Revision Notes
4 revision notes, in the order the specification teaches them.
Dynamic Equilibrium
Dynamic equilibrium: reversible reactions, equal forward and reverse rates, constant concentrations, closed systems and the position of equilibrium.
Start revisingLe Chatelier’s Principle
Le Chatelier’s principle: temperature, pressure and concentration changes, catalysts, and the ammonia and chromate equilibria as examples.
Start revisingEquilibria in Industry
Equilibria in industry: the Haber and Contact processes, compromise temperature and pressure, catalysts and evaluating yield data.
Start revisingThe Equilibrium Constant Kc
Kc: expressions, units, calculations from equilibrium amounts, the magnitude of Kc and the effect of temperature.
Start revisingSummary Map
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Equilibrium Map
OCR A Level Chemistry A · 3.2.3 Chemical equilibrium
The whole section on one A4 page: dynamic equilibrium, Kc, concentration, pressure, temperature and catalysts, and industrial conditions, with worked examples.
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3.2.3
- a
explanation that a dynamic equilibrium exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction and the concentrations of reactants and products do not change
Revise - b ii
application of le Chatelier's principle for homogeneous equilibria to deduce qualitatively the effect of a change in temperature on the position of equilibrium
Revise - b iii
application of le Chatelier's principle for homogeneous equilibria to deduce qualitatively the effect of a change in pressure on the position of equilibrium
Revise - b iv
application of le Chatelier's principle for homogeneous equilibria to deduce qualitatively the effect of a change in concentration on the position of equilibrium
Revise - c
explanation that a catalyst increases the rate of both forward and reverse reactions in an equilibrium by the same amount resulting in an unchanged position of equilibrium
Revise - d i
the techniques and procedures used to investigate changes to the position of equilibrium for changes in concentration
Revise - d ii
the techniques and procedures used to investigate changes to the position of equilibrium for changes in temperature
Revise - e
explanation of the importance to the chemical industry of a compromise between chemical equilibrium and reaction rate in deciding the operational conditions
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