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Shapes of Molecules

Use this landing page to move quickly between the main shapes of molecules revision pages for Cambridge Topic 3. Each card links to a focused page covering molecular geometry, bonding pairs, lone pairs, bond angles and VSEPR-based shape prediction.

AS Level
Topic 3: Chemical Bonding
9701 Papers 1 and 2
Dr. Mohammed Al-Fatah

Written by:
Dr. Mohammed Al-Fatah

Chemistry specialist revision notes for A Level Chemistry.

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1

Choose a Shapes of Molecules Page

Molecular shape depends on the number of bonding pairs and lone pairs around a central atom. These pages separate the key geometries so that students can revise electron-pair repulsion, bond angles and how lone pairs change the final shape.

Key idea: Electron pairs repel each other and arrange themselves as far apart as possible. Lone pairs repel more strongly than bonding pairs, so they reduce bond angles and can change the observed molecular shape.

Shapes of Molecules
Linear
two bonding pairs, 180°
1
Available

Linear

Revise linear molecules with two bonding regions around the central atom and a bond angle of 180°.

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Shapes of Molecules
Trigonal Planar
three bonding pairs, 120°
2
Available

Trigonal Planar

Learn trigonal planar geometry, where three bonding regions arrange at 120° around the central atom.

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Shapes of Molecules
Tetrahedral
four bonding pairs, 109.5°
3
Available

Tetrahedral

Revise tetrahedral molecules with four bonding pairs and bond angles of about 109.5°.

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Shapes of Molecules
Trigonal Pyramidal
three bonding pairs, one lone pair, 107°
4
Available

Trigonal Pyramidal

Understand how one lone pair changes a tetrahedral electron-pair arrangement into a trigonal pyramidal shape.

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Shapes of Molecules
Bent
two bonding pairs, two lone pairs, 104.5°
5
Available

Bent

Learn how lone pairs compress bond angles and produce bent or V-shaped molecules such as H₂O.

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Shapes of Molecules
Trigonal Bipyramidal
five bonding pairs, 120° and 90°
6
Available

Trigonal Bipyramidal

Revise five-region electron-pair geometry with axial and equatorial positions.

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Shapes of Molecules
Octahedral
six bonding pairs, 90°
7
Available

Octahedral

Learn octahedral geometry, where six bonding regions arrange at 90° around the central atom.

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Shapes of Molecules
Square Planar
four bonding pairs, two lone pairs, 90°
8
Available

Square Planar

Revise square planar shapes formed from octahedral electron-pair arrangements with two opposite lone pairs.

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Shapes of Molecules
Square Pyramidal
five bonding pairs, one lone pair
9
Available

Square Pyramidal

Understand square pyramidal molecules and how one lone pair affects an octahedral arrangement.

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Shapes of Molecules
Distorted T
three bonding pairs, two lone pairs
10
Available

Distorted T

Learn distorted T-shaped molecules where lone pairs alter the arrangement of bonding pairs around the central atom.

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Shapes of Molecules
SeeSaw
four bonding pairs, one lone pair
11
Available

SeeSaw

Revise seesaw shapes formed from trigonal bipyramidal electron-pair arrangements with one lone pair.

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How to Use These Pages

Start with the simpler two-, three- and four-region shapes before moving to structures with lone pairs. Then use the higher-coordinate examples to compare trigonal bipyramidal and octahedral electron-pair arrangements.

Exam focus: State the number of bonding pairs and lone pairs first, then give the shape and bond angle. When lone pairs are present, explain that lone pair–bond pair repulsion is stronger than bond pair–bond pair repulsion.

Copyright notice: This revision page, including its written explanations, layout and teaching sequence, is produced for Online Learning System by Dr. Mohammed Al-Fatah. It is intended for student revision and may not be copied, redistributed or republished without permission.