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Edexcel A Level Chemistry

Topic 8
Energetics I

Topic 8 introduces the heat energy changes that accompany chemical reactions. It covers exothermic and endothermic reactions, enthalpy level diagrams and reaction profiles, standard conditions and the standard enthalpy change definitions, measuring enthalpy changes by calorimetry, Hess’s law and enthalpy cycles, and mean bond enthalpies. The practical side is assessed in Core Practical 8.

Exam Paper
Paper 1
9CH0/01
Specification Points
8.1 – 8.11
11 points covered
Topic Parts
5 pages
Revision notes available
Exam Board
Edexcel
Pearson 9CH0
Specification Coverage

Topic 8 Energetics I – Edexcel A Level Chemistry

The following specification points outline the knowledge and skills students are expected to demonstrate for Topic 8. Energetics I is extended in Topic 13 Energetics II.

Enthalpy Changes and Standard Conditions

8.1
know that standard conditions are 100 kPa and a specified temperature, usually 298 K
8.2
know that the enthalpy change is the heat energy change measured at constant pressure
8.3
be able to construct and interpret enthalpy level diagrams showing an enthalpy change, including appropriate signs for exothermic and endothermic reactions; activation energy is shown in reaction profile diagrams but not in enthalpy level diagrams

Standard Enthalpy Changes

8.4
be able to define standard enthalpy change of:
i
reaction
ii
formation
iii
combustion
iv
neutralisation

Measuring Enthalpy Changes

8.5
understand experiments to measure enthalpy changes in terms of:
i
processing results using the expression: energy transferred = mass × specific heat capacity × temperature change (Q = mcΔT)
ii
evaluating sources of error and assumptions made in the experiments
8.6
be able to calculate enthalpy changes in kJ mol⁻¹ from given experimental results; both a sign and units are expected in the final answer

Hess’s Law

8.7
be able to construct enthalpy cycles using Hess’s Law
8.8
be able to calculate enthalpy changes from data using Hess’s Law

Bond Enthalpies

8.9
know what is meant by the terms ‘bond enthalpy’ and ‘mean bond enthalpy’
8.10
be able to calculate an enthalpy change of reaction using mean bond enthalpies and explain the limitations of this method of calculation
8.11
be able to calculate mean bond enthalpies from enthalpy changes of reaction