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OCR A Level Chemistry A – Module 5 Physical Chemistry and Transition Elements

5.1.3
Acids, Bases
and Buffers

Section 5.1.3 covers Brønsted–Lowry acids and bases, conjugate pairs and the basicity of acids, the role of H⁺ in acid reactions, Ka and pKa, pH and the ionic product of water, pH calculations for strong acids, strong bases and weak acids and the limits of the approximations, buffer solutions, how they are made and how they control pH, the blood buffer, pH titration curves and indicators, and measuring pH with a pH meter.

Exam Paper
Paper 1 & 3
H432/01 and H432/03
Learning Outcomes
5.1.3 (a) – (o)
15 learning outcomes
Sub-topics
8 lessons
Revision notes available
Exam Board
OCR
H432 (2015 onwards)

Revision Notes

8 revision notes, in the order the specification teaches them.

A proton passing from an acid to a water molecule
1

Brønsted–Lowry Acids, Bases and Conjugate Pairs

Brønsted–Lowry acids and bases: proton donors and acceptors, proton transfer, conjugate acid-base pairs and water as an acid and a base, and the basicity of acids.

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A drop of indicator falling into a flask above a pH colour scale
2

pH and Strong Acids

PH and strong acids: pH = −log[H⁺], [H⁺] = 10⁻ᵖᴴ, strong and weak acids, and calculating the pH of strong acids.

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The hydronium and hydroxide ions formed from water
3

The Ionic Product of Water, Kw, and Strong Bases

The ionic product of water: Kw = [H⁺][OH⁻], pKw, the effect of temperature on Kw and neutral pH, and the pH of strong bases.

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A beaker of mostly whole acid molecules with a few split ones
4

Weak Acids: Ka and pKa

Weak acids: the Ka expression, pKa, calculating the pH of a weak acid, finding Ka from pH, and the limits of the approximations.

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An S-shaped pH curve with a steep vertical section
5

pH Titration Curves and Indicators

PH titration curves and indicators: the four acid-base combinations, equivalence points, pKa from half-neutralisation and choosing a suitable indicator.

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A drop falling into a solution that keeps a steady level
6

Buffer Solutions: How They Work and Why They Matter

Buffer solutions: making acidic buffers, how a buffer resists pH change, and the blood buffer system.

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An acid and its salt mixed in a beaker with a pH probe
7

Calculating the pH of a Buffer Solution

Calculating buffer pH: [H⁺] = Ka × [HA]/[A⁻], buffers by partial neutralisation, making a buffer of a given pH, and pH after adding acid or alkali.

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A pH probe in a stirred beaker
8

Measuring pH and Finding Ka by Experiment

Measuring pH and finding Ka: the pH meter, pH of acids, bases and salts, dilution of strong and weak acids, and the half-neutralisation method.

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Summary Map

Download, print and revise the key facts of this topic at a glance.

Summary maps

Download, print and revise the key facts of this topic at a glance.

Illustration of a summary map: compounds joined by reaction arrows
Summary map · PDF

Acids, Bases and pH Map

OCR A Level Chemistry A · 5.1.3 Acids, bases and pH

The whole section on one A4 page: Brønsted–Lowry acids and bases, basicity and the reactions of acids, pH, strong acids, Kw and strong bases.

Download the map6 key ideas + a data table · A4 portrait · print ready
Illustration of a summary map: compounds joined by reaction arrows
Summary map · PDF

Weak Acids Map

OCR A Level Chemistry A · 5.1.3 Weak acids

The whole section on one A4 page: weak acids, Kₐ and pKₐ, the pH of a weak acid and finding Kₐ by experiment.

Download the map6 key ideas + a data table · A4 portrait · print ready
Illustration of a summary map: compounds joined by reaction arrows
Summary map · PDF

Titration Curves Map

OCR A Level Chemistry A · 5.1.3 pH titration curves and indicators

The whole section on one A4 page: measuring a pH titration curve, strong and weak acids and bases, titration calculations and choosing an indicator.

Download the map6 key ideas + a data table · A4 portrait · print ready
Illustration of a summary map: compounds joined by reaction arrows
Summary map · PDF

Buffers Map

OCR A Level Chemistry A · 5.1.3 Buffer solutions

The whole section on one A4 page: what a buffer is, how it works, calculating buffer pH, making a buffer, and blood pH.

Download the map6 key ideas + a data table · A4 portrait · print ready

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5.1.3

  1. a (i) a

    a Brønsted–Lowry acid as a species that donates a proton (see also 2.1.4 Acids)

    Revise
  2. a (i) b

    a Brønsted–Lowry base as a species that accepts a proton (see also 2.1.4 Acids)

    Revise
  3. a (ii)

    use of the term conjugate acid–base pairs

    Revise
  4. a (iii) a

    monobasic acids

    Revise
  5. a (iii) b

    dibasic acids

    Revise
  6. a (iii) c

    tribasic acids

    Revise
  7. b i

    the role of H+ in the reactions of acids with metals, using ionic equations (see also 2.1.4 c, 2.1.5 e)

    Revise
  8. b ii

    the role of H+ in the reactions of acids with carbonates, using ionic equations (see also 2.1.4 c, 2.1.5 e)

    Revise
  9. b iii

    the role of H+ in the reactions of acids with metal oxides, using ionic equations (see also 2.1.4 c, 2.1.5 e)

    Revise
  10. b iv

    the role of H+ in the reactions of acids with alkalis, using ionic equations (see also 2.1.4 c, 2.1.5 e)

    Revise
  11. c (i)

    the acid dissociation constant, Ka, for the extent of acid dissociation (see also 2.1.4 b)

    Revise
  12. c (ii)

    the relationship between Ka and pKa

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  13. d i

    use of the expression for pH as: pH = –log[H+]

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  14. d ii

    use of the expression [H+] = 10^–pH

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  15. e

    use of the expression for the ionic product of water, Kw

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  16. f (i)

    calculations of pH, or related quantities, for strong monobasic acids

    Revise
  17. f (ii)

    calculations of pH, or related quantities, for strong bases, using Kw

    Revise
  18. g i

    calculations of pH for a weak monobasic acid using approximations

    Revise
  19. g ii

    calculations of Ka or related quantities for a weak monobasic acid using approximations

    Revise
  20. h

    limitations of using approximations to Ka related calculations for 'stronger' weak acids

    Revise
  21. i

    a buffer solution as a system that minimises pH changes on addition of small amounts of an acid or a base

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  22. j (i)

    formation of a buffer solution from a weak acid and a salt of the weak acid, e.g. CH3COOH/CH3COONa

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  23. j (ii)

    formation of a buffer solution from excess of a weak acid and a strong alkali, e.g. excess CH3COOH/NaOH

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  24. k

    explanation of the role of the conjugate acid–base pair in an acid buffer solution, e.g. CH3COOH/CH3COO–, in the control of pH

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  25. l i

    calculation of the pH of a buffer solution, from the Ka value of a weak acid and the equilibrium concentrations of the conjugate acid–base pair

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  26. l ii

    calculations of quantities related to the pH of a buffer solution

    Revise
  27. m

    explanation of the control of blood pH by the carbonic acid–hydrogencarbonate buffer system

    Revise
  28. n (i) a

    sketch of the shapes of pH titration curves for combinations of strong and weak acids with strong and weak bases

    Revise
  29. n (i) b

    interpretation of the shapes of pH titration curves for combinations of strong and weak acids with strong and weak bases

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  30. n (ii)

    explanation of the choice of suitable indicators, given the pH range of the indicator

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  31. n (iii)

    explanation of indicator colour changes in terms of equilibrium shift between the HA and A– forms of the indicator

    Revise
  32. o

    the techniques and procedures used when measuring pH with a pH meter

    Revise