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OCR A Level Chemistry A – Module 6 Organic Chemistry and Analysis

6.3.1
Chromatography
and Qualitative
Analysis

These pages cover the chromatography outcomes of section 6.3.1: interpreting one-way TLC chromatograms in terms of Rf values, and interpreting gas chromatograms in terms of retention times and the amounts and proportions of the components in a mixture. The test-tube tests for functional groups (6.3.1(c)) are taught with each functional group.

Exam Paper
Paper 2 & 3
H432/02 and H432/03
Learning Outcomes
6.3.1 (a) – (b)
Chromatography outcomes
Sub-topics
2 lessons
Revision notes available
Exam Board
OCR
H432 (2015 onwards)

Revision Notes

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Chromatography and Tests Map

OCR A Level Chemistry A · 6.3.1 Chromatography and qualitative analysis

The whole section on one A4 page: the two phases, thin-layer chromatography, Rf values, gas chromatography, calibration curves and test-tube tests.

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6.3.1

  1. a

    interpretation of one-way TLC chromatograms in terms of Rf values

    Revise
  2. b (i)

    interpretation of gas chromatograms in terms of retention times

    Revise
  3. b (ii)

    interpretation of gas chromatograms in terms of the amounts and proportions of the components in a mixture

    Revise
  4. c (i)

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify alkenes in an unknown compound by reaction with bromine (see also 4.1.3 f)

  5. c (ii)

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify haloalkanes in an unknown compound by reaction with aqueous silver nitrate in ethanol (see also 4.2.2 a)

  6. c (iii)

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify phenols in an unknown compound by weak acidity but no reaction with CO32– (see also 6.1.1 h)

  7. c (iv)

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify carbonyl compounds in an unknown compound by reaction with 2,4-DNP (see also 6.1.2 d)

    Revise
  8. c (v)

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify aldehydes in an unknown compound by reaction with Tollens' reagent (see also 6.1.2 e)

    Revise
  9. c (vi) a

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify primary and secondary alcohols in an unknown compound by reaction with acidified dichromate (see also 4.2.1 c)

  10. c (vi) b

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify aldehydes in an unknown compound by reaction with acidified dichromate (see also 6.1.2 a)

  11. c (vii)

    qualitative analysis of organic functional groups on a test-tube scale; processes and techniques needed to identify carboxylic acids in an unknown compound by reaction with CO32– (see also 6.1.3 b)

    Revise