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Cambridge International AS & A Level Chemistry

Topic 10
Group 2

Topic 10 covers the reactions of the Group 2 elements with oxygen, water and dilute acids, the reactions of their oxides, hydroxides and carbonates with water and acids, the thermal decomposition of the nitrates and carbonates and the trend in stability, the variation in solubility of the hydroxides and sulfates, and predictions from these trends. Group 1 is kept on the pages for comparison; the tests for ions page supports the qualitative analysis in the practical papers.

Exam Papers
Papers 1 & 2
9701 AS Level
Learning Outcomes
10.1.1 – 10.1.5
5 outcomes covered
Topic Parts
6 pages
Revision notes available
Exam Board
Cambridge
9701 (2025 onwards)

Revision Notes

Work through Topic 10 Group 2 in a structured sequence.

Down the group
Group
Trends
1
Available

Trends Down Groups 1 and 2

The trends down Group 2: atomic radius, ionisation energies, melting points and the increase in reactivity down the group.

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The elements
Metal
Reactions
2
Available

Reactions of the Group 1 and 2 Elements

The reactions of the Group 2 elements with oxygen, chlorine, water, steam and dilute acids, with equations, observations and redox analysis.

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Bases
Oxides and
Hydroxides
3
Available

Oxides, Hydroxides and Carbonates

Group 2 oxides, hydroxides and carbonates: reactions with water and acids, pH trend, and uses of Ca(OH)₂, Mg(OH)₂ and CaCO₃.

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Opposite trends
Solubility
Trends
4
Available

Solubility Trends and the Sulfate Test

Group 2 solubility trends: hydroxides and sulfates, Mg(OH)₂ and BaSO₄, the acidified barium chloride test for sulfate ions and barium meals.

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Heat and light
Thermal
Stability
5
Available

Thermal Stability and Flame Colours

Thermal stability of Group 1 and 2 nitrates and carbonates, polarisation by the cation, the experiments, and flame colours explained by electron transitions.

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Qualitative analysis
Tests for
Ions
6
Available

Tests for Ions

Tests for carbonate, hydrogencarbonate, sulfate, halide and ammonium ions, with ionic equations and the order of tests on an unknown.

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Specification Coverage

Topic 10 Group 2 – Cambridge International AS Level Chemistry

The following Cambridge learning outcomes state what candidates should be able to do. Wording is taken from the Cambridge International AS & A Level Chemistry (9701) syllabus.

10.1 Similarities and trends in the properties of the Group 2 metals and their compounds

10.1.1
describe, and write equations for, the reactions of the elements with oxygen, water and dilute hydrochloric and sulfuric acids
10.1.2
describe, and write equations for, the reactions of the oxides, hydroxides and carbonates with water and with dilute hydrochloric and sulfuric acids
10.1.3
describe, and write equations for, the thermal decomposition of the nitrates and carbonates, and describe the trend in thermal stability
10.1.4
describe, and make predictions from, the trends in physical and chemical properties of the elements and compounds in 10.1.1 to 10.1.5
10.1.5
state the variation in the solubilities of the hydroxides and sulfates