Concentrations of Solutions
A focused AQA revision guide to concentrations of solutions. This page covers concentration in mol dm−3, volume conversions, ion concentrations from dissociation, calculations involving solutions and dilution problems with worked examples.
GCSE Recap: Concentration in g dm⁻³
Before you start, check that you can convert volumes and work out a concentration in grams per dm³.
How to Work With Solution Concentrations
The concentration of a solution tells you the amount of solute dissolved in a given volume of solution. In A Level Chemistry, concentration is usually measured as amount of substance, n, per dm3 of solution.
n = cV
The standard units you need to know are:
| Quantity | Symbol | Standard unit | Calculation note |
|---|---|---|---|
| Concentration | c | mol dm−3 | Use with V in dm3 |
| Amount of substance | n | mol | Use as n |
| Volume | V | dm3 | Convert from cm3 if needed |
Volume conversions you must memorise:
cm3 → dm3: divide by 1000
cm3 → m3: divide by 1 000 000
dm3 → m3: divide by 1000
Unit rule: concentration in mol dm−3 uses volume in dm3. Convert cm3 to dm3 before substituting.
Quick Check: Units and Volume Conversions
Answer five quick questions on converting volumes and using concentration = amount ÷ volume.
The concentration equation is short to write and easy to misuse; the real test is whether you can convert the volume to dm3 cleanly every time.
Calculating Concentration From a Known Mass
Most concentration questions give you a mass of solute and a volume of solution. The strategy is always the same: convert the mass to amount of substance first, then divide by the volume in dm3.
Example A – Small-scale solution
Calculate the concentration of the solution made by dissolving 5.00 g of Na2CO3 in water and making the solution up to 250 cm3.
Mr(Na2CO3) = (23.0 × 2) + 12 + (16 × 3) = 106
Example B – Large-scale solution
Calculate the concentration of the solution made by dissolving 10 kg of Na2CO3 in water and making the solution up to 0.50 m3.
Sense check: the two solutions above have almost identical concentrations because the ratio of solute to volume is roughly the same. The actual scale of the solution does not change the concentration; only the ratio does.
Mass Concentration in g dm−3
Concentration can also be given as a mass concentration, which is the mass of solute in grams per dm3 of solution. The unit is g dm−3.
The two types of concentration are linked by Mr, because the mass of 1 mol of solute is Mr in grams.
Worked example: the Na2CO3 solution from Example A
The solution contains 5.00 g of Na2CO3 (Mr = 106) in 250 cm3 of solution.
This matches the answer to Example A, so both routes give the same concentration.
Remember: multiply by Mr to go from mol dm−3 to g dm−3. Divide by Mr to go from g dm−3 to mol dm−3.
Whether the sample is grams in a beaker or kilograms in an industrial tank, the calculation reduces to the same two numbers: amount of solute and volume in dm3.
Alternative Method: Scaling to 1 dm3
Some questions are easier to handle by first scaling the data up to a full 1 dm3 (1000 cm3) of solution, then converting the resulting mass into moles. This is a useful sanity check when the numbers feel awkward.
Example C – Scaling NaHCO3 to 1 dm3
What is the concentration in mol dm−3 of a solution containing 2.10 g of NaHCO3 in 250 cm3 of solution? (H = 1, C = 12, O = 16, Na = 23)
250 cm3 is one quarter of 1000 cm3 (1 dm3). So a solution with the same concentration in 1000 cm3 would contain four times as much solute.
The concentration is therefore 0.100 mol dm−3, which matches the standard c = n ÷ V method.
Choose the method that suits you: the direct c = n ÷ V method is more reliable under exam pressure, but the scaling-to-1-dm3 method is a useful way to check that your answer makes sense.
Quick Check: Concentration From a Mass
Work through six calculations on paper, then flip each card to check your answer and working.
Ion Concentrations From Dissociation
When an ionic compound dissolves in water, it dissociates into its component ions. The concentration of each ion depends on the stoichiometry of the dissociation, not just on the concentration of the original compound.
Example D – Ion concentrations in MgCl2(aq)
If 9.53 g (0.1 mol) of magnesium chloride (MgCl2) is dissolved in water and made up to 1 dm3 of solution, the concentration of magnesium chloride solution would be 0.1 mol dm−3.
However, MgCl2 dissociates fully on dissolving:
MgCl2(s) → Mg2+(aq) + 2Cl−(aq)
So 0.1 mol of MgCl2 produces 0.1 mol of Mg2+ ions and 0.2 mol of Cl− ions.
Rule: the concentration of each ion equals the concentration of the dissolved compound multiplied by the number of those ions in one formula unit. Square brackets, such as [Cl−], are the standard shorthand for “concentration of…”.
Quick Check: Ion Concentrations
Write each dissociation equation on paper, then type the concentration asked for.
One mole of dissolved salt does not always equal one mole of every ion in solution; the dissociation equation is what determines each individual ion concentration.
Basic Calculations From Equations Involving Solutions
When a balanced equation involves a solution, you often need to combine c = n ÷ V with the mole ratio from the equation. The strategy follows three steps:
Step 1 – Find amount of substance of the known substance
For a solution: n = cV. For a solid: n = mass ÷ molar mass.
Step 2 – Apply the mole ratio
Use the coefficients in the balanced equation to convert from the known amount of substance to the required amount of substance.
Step 3 – Convert amount of substance to the required answer
Convert back into mass, volume of solution or concentration depending on what the question asks for.
Example E – Mass of solid reacting with a solution
What is the maximum mass of calcium carbonate that will react with 25.0 cm3 of 2.00 mol dm−3 hydrochloric acid? (C = 12, O = 16, Ca = 40)
Balanced equation: CaCO3 + 2HCl → CaCl2 + H2O + CO2
1 mol of CaCO3 weighs 100 g, so 0.0250 mol weighs 0.0250 × 100 = 2.50 g.
The maximum mass of calcium carbonate is therefore 2.50 g.
Exam tip: in any question where one reactant is given as a volume and concentration of solution, always start by finding the moles of that substance. It is almost always the best starting point.
Quick Check: Reactions Involving Solutions
Use the three-step method on five new reactions, then flip each card to check your working.
Combining concentration with the mole ratio is the workhorse calculation for titration questions and reactant mass questions alike.
Calculating the Volume of a Solution
The concentration equation can be rearranged to find any of the three quantities; concentration, amount or volume.
Use this form whenever you know how many moles of a solute you need and the concentration you are working with.
Example F – Volume needed to deliver a known mass
What volume of 0.500 mol dm−3 NaOH contains 4.00 g of sodium hydroxide? (Na = 23, O = 16, H = 1, so Mr = 40)
Common error: forgetting to convert the final volume to cm3 when the question asks for it. Read the units in the question stem before writing your final answer.
Quick Check: Rearranging the Concentration Formula
Answer three questions on finding a volume or a mass from a concentration.
Rearranging the same single formula is enough to handle nearly every concentration-based question on the paper, provided the units are consistent.
Dilution Calculations
When water is added to a solution, the amount of solute does not change, but the volume increases, so the concentration falls. This is the principle behind every dilution calculation.
Here c1 and V1 are the concentration and volume of the original solution, and c2 and V2 are the concentration and volume of the diluted solution. The units must match on both sides, but they can be in any consistent volume unit (cm3 works fine on both sides).
Example G – Volume of water to add
What volume of water in cm3 must be added to dilute 5.00 cm3 of 1.00 mol dm−3 hydrochloric acid so that it has a concentration of 0.050 mol dm−3?
Critical distinction: the question asks for the volume of water added, not the final total volume. Always subtract the starting volume of solution from the final volume to find the water added.
Quick Check: Dilutions
Answer three questions on what changes, and what does not, when a solution is diluted.
Practically, dilutions are performed in a volumetric flask: a measured volume of stock solution is added, then made up with water to the calibration mark.
Common Exam Points
- Concentration is c = n ÷ V, where n is amount of substance in mol and V is volume in dm3.
- Use concentration units of mol dm−3 unless another unit is specifically requested.
- Always convert cm3 to dm3 by dividing by 1000 before substituting into the formula.
- For solutions, n = cV, with V in dm3; for solids, n = mass ÷ molar mass. Identify which one applies to each substance in the question.
- Ion concentrations depend on the dissociation. For example, in 0.1 mol dm−3 MgCl2, [Mg2+] = 0.1 mol dm−3 and [Cl−] = 0.2 mol dm−3.
- Square brackets, such as [HCl], mean “concentration of HCl” and have units of mol dm−3.
- For reactions involving a solution and a solid, always start by finding the amount of substance you have the most information about.
- For dilutions, use c1V1 = c2V2. Read carefully whether the question asks for the final volume or the volume of water added.
- Show every unit conversion clearly on your script; markers award method marks even if the final number is wrong.
QuickSnap
This text summary condenses the page into the essential exam ideas.
- Concentration formula: concentration = amount ÷ volume, in mol dm−3.
- Volume conversions: cm3 → dm3 divide by 1000; dm3 → m3 divide by 1000; cm3 → m3 divide by 1 000 000.
- Amount in a solution: n = cV, with V in dm3.
- From mass: n = mass ÷ molar mass, then divide by volume in dm3.
- Mass concentration: concentration in g dm−3 = concentration in mol dm−3 × Mr.
- Ion concentrations: determined by the dissociation equation; multiply by the number of those ions per formula unit.
- Square brackets: [X] means concentration of X in mol dm−3.
- Reactions with solutions: use the mole ratio from the balanced equation, after finding amount of substance you know the most about.
- Dilutions: c1V1 = c2V2. The amount of solute does not change; only the volume.
- Volume of water added: final total volume minus starting volume of solution.
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A student prepares a sodium hydroxide solution.
| Quantity | Value |
|---|---|
| Concentration of NaOH | 0.200 mol dm−3 |
| Volume used | 25.0 cm3 |
| Volume in dm3 | 0.0250 dm3 |
What amount of NaOH is present in the 25.0 cm3 sample?
Calculate the mass of CaCO3 that reacts with 25.0 cm3 of 0.200 mol dm−3 HCl.
CaCO3 + 2HCl → CaCl2 + H2O + CO2
FAQs
These questions address the most common points of confusion students encounter when working with solution concentrations.
What unit should I use for concentration?
Use mol dm−3 for concentration unless another unit is specified. Convert volumes in cm3 to dm3 before using c = n ÷ V.
Why do I have to convert cm3 to dm3?
Because the usual concentration unit is mol dm−3. If you leave the volume in cm3, your concentration will be 1000 times too small. Divide every cm3 value by 1000 before substituting into c = n ÷ V.
How do I find the concentration of individual ions in a solution?
Write the dissociation equation for the dissolved compound. The concentration of each ion equals the concentration of the original compound multiplied by the number of those ions in one formula unit. For example, 0.1 mol dm−3 Na2SO4 gives [Na+] = 0.2 mol dm−3 and [SO42−] = 0.1 mol dm−3.
What does c1V1 = c2V2 actually mean?
It states that the amount of solute does not change when a solution is diluted with water. The product of concentration and volume gives the amount of substance, so cV has the same value before and after dilution.
For a reaction involving a solid and a solution, where should I start?
Start with the substance for which you can directly calculate moles. Usually, that is the solution, because you are given its volume and concentration. Once you have amount of substance in the solution, use the mole ratio from the balanced equation to find the amount of substance of the solid, then convert to mass.
Does the volume of a dilution include the original solution?
Yes. In c1V1 = c2V2, V2 is the total final volume of the diluted solution, which includes the original solution plus the added water. The volume of water added is V2 − V1.
Copyright notice: This OLS revision content, including the explanations, layout, diagrams, tables and embedded learning structure, is authored for Online Learning System by Dr. Mohammed Al-Fatah. It may not be copied, reproduced, redistributed or adapted without written permission.
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