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AQA A Level Chemistry

3.1.5
Kinetics

Section 3.1.5 covers collision theory and activation energy, the Maxwell-Boltzmann distribution and its use to explain the effects of temperature and of a catalyst, the meaning of rate and the qualitative effects of concentration and pressure, and how catalysts work. The measuring page supports required practical 3 (initial rate by a clock method).

Exam Paper
Paper 2
7405/2
Specification Points
3.1.5.1 – 3.1.5.5
5 sections covered
Topic Parts
4 pages
Revision notes available
Exam Board
AQA
7405 (2015 onwards)
Specification Coverage

3.1.5 Kinetics – AQA A Level Chemistry

The following AQA specification points outline the knowledge and skills students are expected to demonstrate. Wording follows the AQA A Level Chemistry (7405) specification.

3.1.5 Kinetics

3.1.5.1
Collision theory
i
Reactions can only occur when collisions take place between particles having sufficient energy.
ii
Define the term activation energy.
iii
Explain why most collisions do not lead to a reaction.
3.1.5.2
Maxwell-Boltzmann distribution
i
The Maxwell-Boltzmann distribution of molecular energies in gases.
ii
Draw and interpret distribution curves for different temperatures.
3.1.5.3
Effect of temperature on reaction rate
i
The meaning of the term rate of reaction.
ii
The qualitative effect of temperature changes on the rate of reaction.
iii
Use the Maxwell-Boltzmann distribution to explain why a small temperature increase can lead to a large increase in rate.
3.1.5.4
Effect of concentration and pressure
i
The qualitative effect of changes in concentration on collision frequency and reaction rate.
ii
The qualitative effect of changes in pressure of a gas on collision frequency and reaction rate.
RP 3
Investigation of how the rate of a reaction changes with temperature.
3.1.5.5
Catalysts
i
A catalyst increases the rate of a chemical reaction without being changed in chemical composition or amount.
ii
Catalysts work by providing an alternative reaction route of lower activation energy.
iii
Use a Maxwell-Boltzmann distribution to explain how a catalyst increases the rate of a reaction involving a gas.