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Shapes of Molecules

Use this landing page to move quickly between the main shapes of molecules revision pages for Edexcel Topic 2. Each card links to a focused page covering molecular geometry, bonding pairs, lone pairs, bond angles and VSEPR-based shape prediction.

Unit: Paper 1
Topic 2: Bonding and Structure
9CH0/01
Dr. Mohammed Al-Fatah

Written by:
Dr. Mohammed Al-Fatah

Chemistry specialist revision notes for A Level Chemistry.

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1

Choose a Shapes of Molecules Page

Molecular shape depends on the number of bonding pairs and lone pairs around a central atom. These pages separate the key geometries so that students can revise electron-pair repulsion, bond angles and how lone pairs change the final shape.

Key idea: Electron pairs repel each other and arrange themselves as far apart as possible. Lone pairs repel more strongly than bonding pairs, so they reduce bond angles and can change the observed molecular shape.

Linear
X—A—X
2 BP 0 LP 180°
1
Available

Linear

Revise linear molecules with two bonding regions around the central atom and a bond angle of 180°.

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Trigonal planar
AX₃
3 BP 0 LP 120°
2
Available

Trigonal Planar

Learn trigonal planar geometry, where three bonding regions arrange at 120° around the central atom.

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Tetrahedral
AX₄
4 BP 0 LP 109.5°
3
Available

Tetrahedral

Revise tetrahedral molecules with four bonding pairs and bond angles of about 109.5°.

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One lone pair
AX₃E
3 BP 1 LP ~107°
4
Available

Trigonal Pyramidal

Understand how one lone pair changes a tetrahedral electron-pair arrangement into a trigonal pyramidal shape.

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Two lone pairs
AX₂E₂
2 BP 2 LP ~104.5°
5
Available

Bent

Learn how lone pairs compress bond angles and produce bent or V-shaped molecules such as H₂O.

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Five regions
AX₅
5 BP 0 LP 90° / 120°
6
Available

Trigonal Bipyramidal

Revise five-region electron-pair geometry with axial and equatorial positions.

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Six regions
AX₆
6 BP 0 LP 90°
7
Available

Octahedral

Learn octahedral geometry, where six bonding regions arrange at 90° around the central atom.

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Opposite lone pairs
AX₄E₂
4 BP 2 LP 90°
8
Available

Square Planar

Revise square planar shapes formed from octahedral electron-pair arrangements with two opposite lone pairs.

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One lone pair
AX₅E
5 BP 1 LP ~90°
9
Available

Square Pyramidal

Understand square pyramidal molecules and how one lone pair affects an octahedral arrangement.

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Two lone pairs
AX₃E₂
3 BP 2 LP ~90°
10
Available

Distorted T

Learn distorted T-shaped molecules where lone pairs alter the arrangement of bonding pairs around the central atom.

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One lone pair
AX₄E
4 BP 1 LP <90° / <120°
11
Available

SeeSaw

Revise seesaw shapes formed from trigonal bipyramidal electron-pair arrangements with one lone pair.

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How to Use These Pages

Start with the simpler two-, three- and four-region shapes before moving to structures with lone pairs. Then use the higher-coordinate examples to compare trigonal bipyramidal and octahedral electron-pair arrangements.

Exam focus: State the number of bonding pairs and lone pairs first, then give the shape and bond angle. When lone pairs are present, explain that lone pair–bond pair repulsion is stronger than bond pair–bond pair repulsion.

Copyright notice: This revision page, including its written explanations, layout and teaching sequence, is produced for Online Learning System by Dr. Mohammed Al-Fatah. It is intended for student revision and may not be copied, redistributed or republished without permission.