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Edexcel A Level Chemistry

Empirical and Molecular Formulae

Empirical and molecular formulae connect experimental composition data with the actual formula of a compound. These pages build from finding the simplest whole-number ratio of atoms through to using relative molecular mass to scale up to the true molecular formula.

Exam Paper
Paper 1
9CH0/01
Specification Points
5.4 – 5.5
2 points covered
Sub-topics
2 lessons
Revision notes available
Exam Board
Edexcel
Pearson 9CH0

Summary map

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Empirical and Molecular Formulae Map

Edexcel A Level Chemistry · Topic 5 Formulae, Equations and Amounts of Substance · Empirical and Molecular Formulae

The whole section on one A4 page: empirical formulae from masses and percentages, awkward ratios, molecular formulae and combustion analysis.

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Specification Coverage

Empirical and Molecular Formulae – Edexcel A Level Chemistry

The following specification points outline the knowledge and skills students are expected to demonstrate for Topic 5. Ideas from this topic are applied across quantitative chemistry, practical work and later physical, inorganic and organic topics.

Chemical Language and Formulae

5.4
know what is meant by the terms empirical formula and molecular formula
5.5
be able to use experimental data to calculate empirical formulae and molecular formulae, including the use of pV = nRT for gases and volatile liquids.
i
empirical formulae
ii
molecular formulae including the use of pV = nRT for gases and volatile liquids
Calculations of empirical formula may involve composition by mass or percentage composition by mass data.